SYNTHESIS OF 3-AMINOPYRROLIDIN-2-ONES BY AN INTRAMOLECULAR REACTION OF AZIRIDINECARBOXAMIDES

Funaki I.; Zwanenburg B.; Thijs L.

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SYNTHESIS OF 3-AMINOPYRROLIDIN-2-ONES BY AN INTRAMOLECULAR REACTION OF AZIRIDINECARBOXAMIDES

机译：氮丙啶酰胺的分子内反应合成3-氨基吡咯烷酮-2-酮

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The synthesis of 4,5-disubstituted-3-amino-gamma-lactams from N-substituted aziridinecarboxamides is described. Bicyclic aziridine derivatives were obtained from 1-N-Boc-aziridinecarboxamides under kinetically controlled conditions. Oxiranecarboxamides showed similiar behavior and gave 3-hydroxy-lactams. Copyright (C) 1996 Elsevier Science Ltd [References: 62]

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《Tetrahedron》 |1996年第29期|共16页
作者
Funaki I.; Zwanenburg B.; Thijs L.;
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正文语种 eng
中图分类有机化学;
关键词
Gamma-lactam; 2-aziridinecarboxylic acid; Stereoselective route; Convenient synthesis; Selective synthesis; Crystal-structure; Cyclic-peptides; Turn mimetics; Amino-acids; L-threonine;

机译：γ-内酰胺;2-氮丙啶羧酸;立体选择性途径;简便合成;选择性合成;晶体结构;环肽;Turn模拟物;氨基酸;L-苏氨酸;

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1. SYNTHESIS OF 3-AMINOPYRROLIDIN-2-ONES BY AN INTRAMOLECULAR REACTION OF AZIRIDINECARBOXAMIDES [J] . Funaki I., Zwanenburg B., Thijs L. Tetrahedron . 1996,第29期

机译：氮丙啶酰胺的分子内反应合成3-氨基吡咯烷酮-2-酮
2. DIASTEREOSELECTIVE SYNTHESIS OF TRANS-1,2-DISUBSTITUTED CYCLOPROPANOLS FROM HOMOALLYL OR BIS-HOMOALLYL ESTERS VIA TANDEM INTRAMOLECULAR NUCLEOPHILIC ACYL SUBSTITUTION AND INTRAMOLECULAR CARBONYL ADDITION REACTIONS MEDIATED BY TI(OPR-I)(4)/2 I-PRMGBR [J] . Kasatkin A., Sato F. Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 1995,第34期

机译：由TI（OPR-I）介导的间苯二酚分子内的核亲酸取代和分子间的羰基加成反应由同烯丙基或双-双烯丙基酯的对映选择性合成反式1,2-取代的环丙醇
3. Intramolecular Nicholas reactions in the synthesis of dibenzocycloheptanes. Synthesis of allocolchicine NSC 51046 and analogues and the formal synthesis of (-)-allocolchicine [J] . Djurdjevic S., Yang F., Green J.R. The Journal of Organic Chemistry . 2010,第23期

机译：二苯并环庚烷合成中的分子内尼古拉斯反应。 allocolchicine NSC 51046及其类似物的合成和（-）-allocolchicine的形式合成
4. Highly Efficient Synthesis of Oxindole Derivatives via Catalytic Intramolecular C-H Insertion Reactions of Diazoamides [C] . Nga Phan-Thi-Thanh, Masaya Tone, Hayato lnoue International Conference on Science and Technology . 2020

机译：通过催化分子内C-H插入式重氮酰胺的催化分子内C-H插入反应高效合成氧吲哚衍生物
5. An application of the intramolecular Heck reaction: A new strategy in the synthesis of Hasubanan alkaloids. Preparation of unsymmetrical biaryls via the Stille cross-coupling reaction: Synthesis of highly functional intermediates towards the synthesis of vindoline. [D] . Frank, Anthony Joseph. 2002

机译：分子内Heck反应的应用：合成Hasubanan生物碱的新策略。通过Stille交叉偶联反应制备不对称的联芳基：合成高功能性中间体，合成长春新碱。
6. Synthesis of pyrrolidinedione-fused hexahydropyrrolo21-aisoquinolines via three-component 3 + 2 cycloaddition followed by one-pot N-allylation and intramolecular Heck reactions [O] . Xiaoming Ma, Suzhi Meng, Xiaofeng Zhang, 2020

机译：通过三分组分3 + 2环加入合成吡咯烷二酮熔融六氢吡咯烷21-A异喹啉然后是单罐N-烯丙基化和分子内的静脉反应
7. Intramolecular Nicholas Reactions in the Synthesis of Dibenzocycloheptanes. Synthesis of Allocolchicine NSC 51046 and Analogues and the Formal Synthesis of (−)-Allocolchicine [O] . Djurdjevic Sinisa, Yang Fei, Green James R. 2010

机译：二苯并环庚烷合成中的分子内尼古拉斯反应。 NSC 51046及其同系物的合成及（-）-Alocolchicine的形式合成

SYNTHESIS OF 3-AMINOPYRROLIDIN-2-ONES BY AN INTRAMOLECULAR REACTION OF AZIRIDINECARBOXAMIDES

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