ADDITION OF HYDROGEN HALIDES TO ACETYLENIC SELENIDES - SYNTHESIS OF 1-HALO-1-SELENOALKENES

摘要

Acetylenic selenides react with HX (X=Cl, Br, I) at room temperature to give 1-halo-1-selenoalkenes in good yields. The 1-iodo-1-selenoalkenes were transformed into the corresponding vinylic organometallics (M=Zn, Cu, Cr). Copyright (C) 1996 Elsevier Science Ltd. [References: 27]