In situ Synthesis and mechanical, thermal properties of polyimide nanocomposite film by addition of functionalized graphene oxide

摘要

Polyimide (PI) and chemical modified graphene oxide nanocomposite films are prepared by in situ polymerization from solutions of pyromellitic dianhydride and 4,4-oxydianiline with various amount (0.5-2 wt%) of 3-aminopropyltriethoxysilane (APTS) functionalized graphene oxide (GO) sheets in dimethylacetamide. The APTS functionalized GO (GO-APTS) is a versatile platform for polymer grafting, improving excellent dispersion of GO in the PI matrix, and forming strong interaction with the PI matrix. The GO-APTS/PI nanocomposites exhibited improvement in mechanical and thermal properties by addition of a small amount of GO-APTS. With the addition of a small amount of GO-APTS (1.5 wt%) to PI matrix, mechanical properties with the tensile strength and Young's modulus improved by 45% and 15%, respectively. The thermal analysis showed that the thermal stability of PI was slightly enhanced by the incorporation of GO-APTS (1.5 wt%). This approach provides a strategy for developing high performance functionalized GO-polymer composite materials. POLYM. COMPOS., 37:907-914, 2016. (c) 2014 Society of Plastics Engineers