Properties of Carbon Fiber and Composites Modified With Different-Sized Graphene Oxide Sheets

摘要

The graphene oxide (GO) sheets with different size distributions were effectively separated by a centrifugation method. The exfoliated single-layer structure and the size of GO sheets were verified by scanning electron microscopy (SEM), atomic force microscope (AFM), and metallurgical microscope, respectively. Two different-sized GO sheets water suspensions were obtained, which were then directly dispersed in carbon fiber (CF) sizing agent, respectively. The influences of the different-sized GO sheets on CF and CF composites were explored. The workability in later process of CF and CF surface morphology were characterized by abrasion resistance, fluffs and breakage, stiffness, and SEM. SEM micrographs demonstrated that a nonuniform distribution of the large-sized GO was lapped on CF whereas the small-sized GO was uniformly leaned on CF. The interlaminar shear strength of the small-sized GO/CF reinforced composite could reaches the maximum value. It indicated that the interfacial region between CF and polymer matrix could be enhanced by adjusting the size of GO sheets. (C) 2015 Society of Plastics Engineers