Preparation and Characterization of Low-Density Polyethylene/Thermoplastic Starch Composites Reinforced by Cellulose Nanofibers

摘要

In the current study, the effect of extracted cellulose nanofibers (CNFs) on rheological and mechanical properties and biodegradability of polyethylene/starch blend was investigated. The CNFs were extracted from wheat straws using a chemo-mechanical method. Polyethylene/starch blend was reinforced by different amounts of CNF (6-14 wt%) using an internal mixer followed by a single screw extruder. The flow properties of nanocomposites were investigated by determining Melt Flow Index (MFI) and viscosity. Due to the weak interaction of cellulosic nanofibers and polymers, the flow behavior of nanocomposites was undesirable. Tensile tests were performed to evaluate the mechanical performance of nanocomposites. By increasing the CNF content, the tensile strength and elongation at break declined; whereas, the Young's modulus was improved. The biodegradation of cellulose nanocomposites was investigated by water absorption and degradability tests. Both experiments confirmed the progressive effect of cellulose nanofibers on the degradation of the composites. (C) 2014 Society of Plastics Engineers