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Molecular wave-packet dynamics on laser-controlled transition states

机译:激光控制过渡态下的分子波包动力学

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We present a kinematically complete and time-resolved study of the dissociation dynamics of H-2+ using ultrashort extreme-ultraviolet and near-infrared laser pulses. The reaction kinematics can be controlled by varying the time delay between the two pulses. We demonstrate that a time-dependent laser-dressed potential-energy curve enables the control of the nuclear motion. The dynamics is well reproduced by intuitive semiclassical trajectories on a time-dependent potential curve. From this most fundamental scenario we gain insight in the underlying mechanisms which may be applied as design principles for molecular quantum control, particularly for ultrafast molecular reactions involving the motion of protons.
机译:我们提出了使用超短波极紫外和近红外激光脉冲对H-2 +进行解离动力学的运动学完整且时间分辨的研究。可以通过改变两个脉冲之间的时间延迟来控制反应运动学。我们证明了随时间变化的激光修正的势能曲线能够控制核运动。通过直观的半古典轨迹在与时间相关的电位曲线上可以很好地再现动力学。从这个最基本的场景中,我们了解了可能用作分子量子控制(尤其是涉及质子运动的超快分子反应)设计原理的潜在机理。

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