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NEW CERMET SOLAR COATINGS FOR SOLAR THERMAL ELECTRICITY APPLICATIONS

机译:太阳能热电应用的新型金属陶瓷涂层

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On the basis of successful research into new metal-aluminium nitride (M-AlN) cermet solar selective coatings, a commercial-scale cylindrical direct current (dc) magnetron sputter coater has been developed for the deposition of these cermet solar coatings onto batches of tubes. The coater vacuum chamber has a diameter of 0.8 m and is 1.8 m in height. 32 glass tubes may be accommodated in the chamber. Stainless steel-aluminium nitride (SS-AlN) cermet material has been investigated as a solar absorbing layer. Three cylindrical post cathodes, consisting of stainless steel, aluminium and copper tubes, are installed in the chamber. During the deposition of an SS-AlN cermet layer, both the Al and SS targets are sputtered simultaneously in the gas mixture of argon and nitrogen. The nitrogen partial pressure is set sufficiently high at the aluminium target side to ensure that a nearly pure AlN ceramic sublayer is deposited by dc reactive sputtering. The planetary rotation of the 32 tubes results in a multi-layered system consisting of alternating SS and AlN sublayers. This multi-sublayer system can be considered as a macro-homogeneous cermet layer. Varying SS target current achieves different SS volume fractions in the cermet layers. A solar absorptance of 0.94-0.95 and emittance of 0.04-0.05 at room temperature has been achieved for the SS-AlN cermet solar coatings. These solar tubes are stable at 330-400℃. Using this commercial-scale coater, it should be possible to produce solar tubes stable at even higher temperatures (450-550℃), based on a high melting point transition metal-aluminium nitride cermet.
机译:在成功研究新型金属氮化铝(M-AlN)金属陶瓷太阳能选择性涂层的基础上,开发了商用规模的圆柱形直流(dc)磁控溅射镀膜机,以将这些金属陶瓷太阳能涂层沉积到成批的管子上。涂布机真空室的直径为0.8 m,高度为1.8 m。腔室内可容纳32个玻璃管。已经研究了不锈钢-氮化铝(SS-AlN)金属陶瓷材料作为太阳能吸收层。室中安装了三个由不锈钢,铝和铜管组成的圆柱后阴极。在沉积SS-AlN金属陶瓷层的过程中,同时在氩气和氮气的混合气体中溅射Al和SS靶。将氮分压设置在铝靶侧足够高,以确保通过直流反应溅射沉积近乎纯净的AlN陶瓷子层。 32根管的行星旋转产生了一个由交替的SS和AlN子层组成的多层系统。该多层系统可以被认为是宏观均匀的金属陶瓷层。 SS目标电流的变化在金属陶瓷层中实现了不同的SS体积分数。 SS-AlN金属陶瓷太阳能涂料在室温下的吸光度为0.94-0.95,发射度为0.04-0.05。这些太阳能管在330-400℃下稳定。使用这种商业规模的涂布机,应该可以生产出基于高熔点过渡金属-氮化铝金属陶瓷的更高温度(450-550℃)稳定的太阳能管。

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