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Effect of fluence of He+ ions on fluorescence intensity of riphenylmethyl radical

机译:He +离子通量对三苯基甲基自由基荧光强度的影响

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摘要

Fluuorescence band ascribed to the triphenylmethyl radical of TPM (triphenylmentane) and TMPOH (triphenylmethanol) in a polymer film were observed by the simultaneous irradiation with He+ Ions from a 200 keV accelerator and 337 nm light from a nitrogen laser. The intensity of the fluorescence Band of triphenylmethyl radical from TPMOH increased up to 2x10~12 ions/cm~2 and then decreased Gradually. From a preliminary analysis, the radius of the chemical track in a polymer film was estimated To be 3.5 nm from the dependence of the fluorescence intensity of the radical on an ion fluence.
机译:通过同时照射来自200 keV促进剂的He +离子和来自氮气激光器的337 nm光,观察到聚合物膜中TPM(三苯甲烷)和TMPOH(三苯甲醇)的三苯甲基自由基的荧光带。 TPMOH发出的三苯基甲基自由基的荧光带强度增加至2x10〜12离子/ cm〜2,然后逐渐降低。根据初步分析,根据自由基的荧光强度与离子通量的相关性,聚合物膜中化学径的半径估计为3.5 nm。

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