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Role of carbon quantum dots and film thickness on enhanced UV shielding capability of flexible polymer film containing carbon quantum dots/N-doped ZnO nanoparticles

机译:碳量子点和膜厚度对包含碳量子点/ N掺杂的ZnO纳米颗粒的柔性聚合物膜增强UV屏蔽能力的作用

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摘要

We report a simple method for preparing flexible polymer film containing carbon quantum dots/N-doped ZnO (CQD/N-ZnO) nanoparticles, as UV shielding material. The polymer film showed an enhanced UV shielding capability with increasing of CQD/N-ZnO nanoparticles. The maximum of 47% of UV shielding capability was achieved with 1 wt.% of CQD/N-ZnO nanoparticles and two-order enhancement was achieved by controlling film thickness to 250 mu m. It was found that CQDs plays important role to promote compatibility of hydrophilic ZnO into hydrophobic polymer matrix without disturbing the transparency of the film. An excellent UV shielding capability of 85% and 92% was witnessed in 250 mu m thick polymer film under a UV lamp and direct daylight, respectively.
机译:我们报告了一种简单的方法来制备柔性聚合物薄膜,该薄膜包含碳量子点/ N掺杂的ZnO(CQD / N-ZnO)纳米粒子,作为紫外线屏蔽材料。随着CQD / N-ZnO纳米颗粒的增加,聚合物膜表现出增强的紫外线屏蔽能力。使用1 wt。%的CQD / N-ZnO纳米粒子可获得最大47%的紫外线屏蔽能力,并且通过将薄膜厚度控制在250μm,可以实现两级增强。发现CQD在促进亲水性ZnO与疏水性聚合物基质的相容性而不破坏膜的透明性方面起重要作用。在紫外线灯和直射日光下,在250微米厚的聚合物薄膜中分别具有85%和92%的出色的紫外线屏蔽能力。

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