Extended X-ray Absorption Fine Structure and Nuclear Resonance Vibrational Spectroscopy Reveal that NifB-co, a FeMo-co Precursor, Comprises a 6Fe Core with an Interstitial Light Atom

Simon J. George; Robert Y. Igarashi; Yuming Xiao; Jose A. Hernandez; Marie Demuez; Dehua Zhao; Yoshitaka Yoda; Paul W. Ludden; Luis M. Rubio; Stephen P. Cramer

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Extended X-ray Absorption Fine Structure and Nuclear Resonance Vibrational Spectroscopy Reveal that NifB-co, a FeMo-co Precursor, Comprises a 6Fe Core with an Interstitial Light Atom

机译：扩展的X射线吸收精细结构和核共振振动光谱显示，NefB-co（FeMo-co前驱体）包含具有间隙光原子的6Fe核

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NifB-co, an Fe-S cluster produced by the enzyme NifB, is an intermediate on the biosynthetic pathway to the iron molybdenum cofactor (FeMo-co) of nitrogenase. We have used Fe K-edge extended X-ray absorption fine structure (EXAFS) spectroscopy together wi

机译：NifB-co是由NifB酶产生的Fe-S簇，是生物合成途径中通往固氮酶的铁钼辅因子（FeMo-co）的中间体。我们已经一起使用Fe K边缘扩展X射线吸收精细结构（EXAFS）光谱

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《Journal of the American Chemical Society》 |2008年第17期|5673-5680|共8页
作者
Simon J. George; Robert Y. Igarashi; Yuming Xiao; Jose A. Hernandez; Marie Demuez; Dehua Zhao; Yoshitaka Yoda; Paul W. Ludden; Luis M. Rubio; Stephen P. Cramer;
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收录信息美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);美国《化学文摘》(CA);
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1. Structural Characterization of CO-Inhibited Mo-Nitrogenase by Combined Application of Nuclear Resonance Vibrational Spectroscopy, Extended X-ray Absorption Fine Structure, and Density Functional Theory: New Insights into the Effects of CO Binding and the Role of the Interstitial Atom [J] . Aubrey D. Scott, Vladimir Pelmenschikov, Yisong Guo, Journal of the American Chemical Society . 2014,第45期

机译：联合应用的核共振振动光谱法，扩展的X射线吸收精细结构和密度泛函理论的CO抑制钼氮酶的结构表征：对CO结合的影响和间质原子的作用的新见解。
2. Hemilability of ether-phosphine in ruthenium(II) complexes: 31P{1H}-nuclear magnetic resonance (NMR), fast atom bombardment-mass spectroscopy (FAB-MS) and extended X-ray absorption fine structure spectroscopy (EXAF) to confirm the open-closed behavior [J] . Ismail Warad, Rawhi Al-Far, Saud Al-Resayes, International Journal of Physical Sciences . 2011,第31期

机译：钌（II）络合物中醚膦的半透明性：31P {1H}-核磁共振（NMR），快速原子轰击质谱（FAB-MS）和扩展的X射线吸收精细结构光谱（EXAF）证实了开闭行为
3. A monomeric [Zr(CO3)(4)](4-) complex in an ammonium zirconium carbonate aqueous solution studied by extended X-ray absorption fine structure, Raman and nuclear magnetic resonance spectroscopy [J] . Takasaki Fumiyuki, Fujiwara Kazuhiko, Nakajima Yasushi, Dalton transactions: An international journal of inorganic chemistry . 2015,第2期

机译：扩展的X射线吸收精细结构，拉曼光谱和核磁共振谱研究了碳酸锆铵水溶液中的单体[Zr（CO3）（4）]（4-）配合物
4. Local environments of Cu atoms in AlCu thin films studied using extended x-ray absorption fine structures [C] . Hirokazu Ezawa, Hideki Hashimoto, HidehikoYabuhara Advanced Metallization Conference . 2000

机译：使用延长的X射线吸收细结构研究了Alcu薄膜中Cu原子的局部环境
5. On the use of extended x-ray absorption fine structure spectroscopy to determine the bonding configurations of orthophosphate surface complexes at the goethite/water interface. [D] . Abdala, Dalton Belchior. 2013

机译：在使用扩展的X射线吸收精细结构光谱学来确定针铁矿/水界面处正磷酸盐表面复合物的键合构型。
6. EXAFS and NRVS Reveal that NifB-co a FeMo-co Precursor Comprises a 6Fe Core with an Interstitial Light Atom [O] . Simon J. George, Robert Y. Igarashi, Yuming Xiao, -1

机译：EXAFS和NRVS揭示了FeMo-co前驱体NifB-co包含具有间隙光原子的6Fe磁芯
7. Structural Characterization of CO-Inhibited Mo-Nitrogenase by Combined Application of Nuclear Resonance Vibrational Spectroscopy, Extended X-ray Absorption Fine Structure, and Density Functional Theory: New Insights into the Effects of CO Binding and the Role of the Interstitial Atom [O] . Aubrey D. Scott, Vladimir Pelmenschikov, Yisong Guo, 2014

机译：核谐振振动光谱，延长X射线吸收细结构和密度泛函理论的组合应用共同抑制的MO-氮酶的结构表征：对CO结合效应的新见解及间隙原子的作用

Extended X-ray Absorption Fine Structure and Nuclear Resonance Vibrational Spectroscopy Reveal that NifB-co, a FeMo-co Precursor, Comprises a 6Fe Core with an Interstitial Light Atom

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