Geochemistry and petrogenesis of late Ediacaran (605-580 Ma) post-collisional alkaline rocks from the Katherina ring complex, south Sinai, Egypt

摘要

The Katherina ring complex (KRC) in the central part of south Sinai, Egypt, is a typical ring complex of late Neoproterozoic age (605-580 Ma). It was developed during the final tectono-magmatic stage of the north Arabian-Nubian Shield (ANS) during evolution of the Pan-African crust. The KRC includes Katherina vol-canics, subvolcanic bodies, ring dykes and Katherina granitic pluton. The Katherina volcanics represent the earliest stage of the KRC, which was subsequently followed by emplacement of the subvolcanic bodies and ring dykes. The Katherina granitic pluton depicts as the latest evolution stage of the KRC that intruded all the early formed rock units in the concerned area. The Katherina volcanics are essentially composed of rhyolites, ignimbrite, volcanic breccia and tuffs. Mineralogically, the peralkaline rhyolites contain sodic amphiboles and aegirine. The rhyolite whole rock chemistry has acmite-normative character. The subvolcanic bodies of the KRC are represented by peralkaline microgranite and porphyritic quartz syenite. The ring dykes are semicircular in shape and consist mainly of quartz syenite, quartz trachyte and trachybasalt rock types. The Katherina subvolcanic rocks, volcanic rocks as well as the ring dykes are alkaline or/and peralkaline in nature. The alkaline granitic pluton forms the inner core of the KRC, including the high mountainous areas of G. Abbas Pasha, G. Bab, G. Katherina and G. Musa. These mountains are made up of alkaline syenogranite and alkali feldspar granite. The mantle signature recorded in the KRC indicates a juvenile ANS crust partial melting process for the generation of this system. The evolution of the KRC rocks is mainly dominated by crystal fractionation and crustal contamination. Mineral geothermometry points to the high temperature character of the KRC, up to 700-1100 ℃.