Cold-rolled magnesium hydride strips decorated with cold-sprayed Ni powders for solid-state - hydrogen storage

摘要

The present work reports for the first time application of cold spray coating for doping plastically deformed Mg-strips by different concentrations of fine Ni powders. For present study, Mg rods were cold-rolled for 300 passes and then coated by Ni fine powders, using a cold spray process operated at 150 degrees C under high argon gas pressure. The Ni powders were pelted into Mg-substrate through the high-velocity jet at a speed of 500 m/s. Under these preparation conditions, Ni powders were plastically deformed at the surface of Mg strips to create numerous pores and cavities, worked as hydrogen diffusion gateway. The as-coated Mg sheets with 3-Ni layers (5.28 wt%) possessed good hydrogenation/dehydrogenation kinetics, implied by a short absorption/desorption time (5.1/11 min) of 6.1 wt% hydrogen at 150 degrees C/10 bar and 200 degrees C/200 mbar, respectively. The fabricated solid-state hydrogen storage nanocomposite strips revealed good cyclability of achieving 600 cycles at 200 degrees C without failure of degradation. (C) 2019 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.