Effect of nitrogen doping on the electrochemical performance of resorcinol-formaldehyde based carbon aerogels as electrode material for supercapacitor applications

摘要

Nitrogen doped resorcinol/formaldehyde carbon aerogels with controlled nitrogen content are synthesized by controlling the resorcinol/melamine molar ratio (R/M) during the synthesis of aerogel precursors. The carbons were used as electrode materials in an electrochemical capacitor using 6 M KOH solution as electrolyte. All samples exhibited amorphous structure with low degree of graphitization. The maximum specific capacitance of 208 Fg(-1) was observed after doping of the carbon with nitrogen at R/M = 80. Drop in solution and charge transfer resistances from 0.570 to 0.150 and 0.050-0.040 was also observed respectively, with the drop in contact angles from 123 to 103 for the carbon doped with nitrogen at R/M = 80. BET results showed that the pore volume and surface area of carbon increase after N-doping, with a BET surface area of 841 m(2) g(-1) at RIM = 80. This R/M ratio is an optimum ratio at which incorporation of nitrogen into the carbon matrix improves the capacitive performance of cell as a result of improved porosity/wettability/conductivity/active sites of the electrode. Doping at higher nitrogen concentrations (RIM 80) decreased the specific capacitance of the cell significantly due to decreased conductivity of carbon and suppression of the hopping rate of dopant. (C) 2019 Elsevier Ltd. All rights reserved.