The giant Bayan Obo REE-Nb-Fe deposit, China: Controversy and ore genesis

摘要

Bayan Obo ore deposit is the largest rare-earth element (REE) resource, and the second largest niobium (Nb) resource in the world. Due to the complicated element/mineral compositions and involving several geological events, the REE enrichment mechanism and genesis of this giant deposit still remains intense debated. The deposit is hosted in the massive dolomite, and nearly one hundred carbonatite dykes occur in the vicinity of the deposit. The carbonatite dykes can be divided into three types from early to late: dolomite, co-existing dolomite-calcite and calcite type, corresponding to different evolutionary stages of carbonatite magmatism based on the REE and trace element data. The latter always has higher REE content. The origin of the ore-hosting dolomite at Bayan Obo has been addressed in various models, ranging from a normal sedimentary carbonate rocks to volcano-sedimentary sequence, and a large carbonatitic intrusion. More geochemical evidences show that the coarse-grained dolomite represents a Mesoproterozoic carbonatite pluton and the fine-grained dolomite resulted from the extensive REE mineralization and modification of the coarse-grained variety. The ore bodies, distributed along an E–W striking belt, occur as large lenses and underwent more intense fluoritization and fenitization. The first episode mineralization is characterized by disseminated mineralization in the dolomite. The second or main-episode is banded and/or massive mineralization, cut by the third episode consisting of aegirine-rich veins. Various dating methods gave different mineralization ages at Bayan Obo, resulting in long and hot debates. Compilation of available data suggests that the mineralization is rather variable with two peaks at ～1400?and 440?Ma. The early mineralization peak closes in time to the intrusion of the carbonatite dykes. A significant thermal event at ca. 440?Ma resulted in the formation of late-stage veins with coarse crystals of REE minerals. Fluids involving in the REE-Nb-Fe mineralization at Bayan Obo might be REE-F-CO 2 -NaCl-H 2 O system. The presence of REE-carbonates as an abundant solid in the ores shows that the original ore-forming fluids are very rich in REE, and therefore, have the potential to produce economic REE ores at Bayan Obo. The Bayan Obo deposit is a product of mantle-derived carbonatitic magmatism at ca. 1400?Ma, which was likely related to the breakup of Columbia. Some remobilization of REE occurred due to subduction of the Palaeo-Asian oceanic plate during the Silurian, forming weak vein-like mineralization. Graphical abstract Display Omitted Highlights ? Carbonatite dyke and dolomite at Bayan Obo were derived from carbonatitic magma. ? Giant Bayan Obo REE-Nb-Fe deposit underwent two-stage mineralization. ? REE-rich ore-forming fluids laid a foundation to form giant REE mineralization.