1,2-HYDROGEN MIGRATION IN AMINOALKYL RADICALS

摘要

The amination reaction of α-olefins C 4 -C 7 in the oxidation-reduction system NН 2 OH?HCl-TiCl 3 has been investigated; as a result the mono- and diamines of various structures have been prepared. It has been found that in attack of -radical to olefin it takes place a hydrogen migration from first carbon to second one. It has been shown that in composition of the reaction products besides purposeful individual amines there are detected telomers, the molecular masses of which are changed approximately within the ranges of, Мn = 460-800.