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(2-Hy-dr-oxy-benzoato-κO)triphen-yl(tri-phenyl-phosphine oxide-κO)tin(IV)

机译:(2-Hy-dr-oxy-benzoatoato-κO)triphen-yl(tri-phenyl-phosphineoxide-κO)tin(IV)

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摘要

The title compound, [Sn{C6H4(OH)COO}(C6H5)3{OP(C6H5)3}], is comprised of discrete molecules with the SnIV atom in a trigonal–bipyramidal coordination environment. The carboxylate O atom of the salicylate anion and the O atom of the triphenylphosphine oxide moiety are in the axial positions and the three ipso C atoms occupy the equatorial positions. An intramolecular O—HO hydrogen bond is present in the anion between the hydroxy group and the carbonyl atom O of the carboxylate group.
机译:标题化合物[Sn {C6H4(OH)COO}(C6H5)3 {OP(C6H5)3}]由在三角形-双锥体配位环境中具有SnIV原子的离散分子组成。水杨酸根阴离子的羧酸根O原子和三苯膦氧化物部分的O原子在轴向位置,并且三个ipso C原子占据赤道位置。羟基与羧酸根的羰基原子O之间的阴离子中存在分子内O-HO氢键。

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