Aqueous asymmetric cyclopropanation reactions in polymersome membranes

Matthijs C. M. van Oers; Loai K. E. A. Abdelmohsen; Floris P. J. T. Rutjes; Jan C. M. van Hest

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Aqueous asymmetric cyclopropanation reactions in polymersome membranes

机译：多聚体膜中的水不对称环丙烷化反应

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摘要

Copper-bis(oxazoline) complexes have been immobilised in the hydro-phobic domain of a polymersome membrane to perform asymmetric cyclopropanation reactions in aqueous media with enhanced conversions and enantiosetectivities.

机译：铜-双（恶唑啉）络合物已固定在聚合物小体膜的疏水域中，可在水性介质中进行不对称环丙烷化反应，并提高转化率和对映异构性。

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《Chemical Communications》 |2014年第31期|4040-4043|共4页
作者
Matthijs C. M. van Oers; Loai K. E. A. Abdelmohsen; Floris P. J. T. Rutjes; Jan C. M. van Hest;
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Institute for Molecules and Materials, Radboud University Nijmegen, Heyendaalseweg 135, 6525 AJ Nijmegen, The Netherlands;

Institute for Molecules and Materials, Radboud University Nijmegen, Heyendaalseweg 135, 6525 AJ Nijmegen, The Netherlands;

Institute for Molecules and Materials, Radboud University Nijmegen, Heyendaalseweg 135, 6525 AJ Nijmegen, The Netherlands;

Institute for Molecules and Materials, Radboud University Nijmegen, Heyendaalseweg 135, 6525 AJ Nijmegen, The Netherlands;

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机译：多聚体膜中的水不对称醛醇缩合反应

Aqueous asymmetric cyclopropanation reactions in polymersome membranes

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