Unprecedented reactivity in the Morita-Baylis-Hillman reaction; intramolecular alpha-alkylation of enones using saturated alkyl halides

Krafft ME; Seibert KA; Haxell TFN; Hirosawa C

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Unprecedented reactivity in the Morita-Baylis-Hillman reaction; intramolecular alpha-alkylation of enones using saturated alkyl halides

机译：Morita-Baylis-Hillman反应中空前的反应性；使用饱和烷基卤化物进行烯类的分子内α-烷基化

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摘要

sp(3) Hybridized electrophiles, never before used in the organo-mediated Morita-Baylis-Hillman reaction, now facilitate the formation of five- and six-membered enone cycloalkylation products.

机译：sp（3）杂交的亲电试剂，以前从未用于有机介导的Morita-Baylis-Hillman反应中，现在促进了五元和六元烯酮环烷基化产物的形成。

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来源
《Chemical Communications》 |2005年第46期|p. 5772-5774|共3页
作者
Krafft ME; Seibert KA; Haxell TFN; Hirosawa C;
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作者单位

Florida State Univ, Dept Chem & Biochem, Tallahassee, FL 32306 USA;

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原文格式 PDF
正文语种 eng
中图分类化学;
关键词
SECONDARY-AMINES; MICHAEL CYCLOISOMERIZATION; NUCLEOPHILIC CATALYSIS; 1; 4-PENTADIENES; METATHESIS; ALDEHYDES; PARTNERS; THIOLS; SCOPE;

机译：二级胺;迈克尔环异构化;亲核催化;1;4-戊二烯;易位;醛;对苯二甲酸;硫醇;范围;

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8. The Temperature Dependence of Triplet State Reaction Rate and Quantum Yield for an Intramolecular Enone Photocycloaddition. [R] . jones, guilford ii ramachandran, bellampalli r. 1976

机译：分子内烯酮光环加成反应的三重态反应速率和量子产率的温度依赖性。

Unprecedented reactivity in the Morita-Baylis-Hillman reaction; intramolecular alpha-alkylation of enones using saturated alkyl halides

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