Unprecedented reduction of the uranyl ion [UO_2]~(2+) into a polyoxo uranium(Ⅳ) cluster: Synthesis and crystal structure of the first f-element oxide with a M_6(μ_3-O)_8 core

Jean-Claude Berthet; Pierre Thuery; Michel Ephritikhine

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Unprecedented reduction of the uranyl ion [UO_2]~(2+) into a polyoxo uranium(Ⅳ) cluster: Synthesis and crystal structure of the first f-element oxide with a M_6(μ_3-O)_8 core

机译：前所未有的将铀酰离子[UO_2]〜（2+）还原为多氧铀（Ⅳ）簇：具有M_6（μ_3-O）_8核的第一f元素氧化物的合成和晶体结构

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The smooth comproportionation reaction of the U(Ⅵ) and U(Ⅲ) complexes UO_2(OTf)_2 and U(OTf)_3, afforded the hexa-nuclear U(Ⅳ) oxide cluster [U_6(μ_3-O)_8(μ_2-OTf)_8(py)_8], a rare example of a metal oxide with a M_6(μ_3-O)-8 core.

机译：U（Ⅵ）和U（Ⅲ）配合物UO_2（OTf）_2和U（OTf）_3的光滑配位反应，得到六核U（Ⅳ）氧化物簇[U_6（μ_3-O）_8（μ_2- OTf）_8（py）_8]，是具有M_6（μ_3-O）-8核的金属氧化物的罕见示例。

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来源
《Chemical Communications》 |2005年第27期|p.3415-3417|共3页
作者
Jean-Claude Berthet; Pierre Thuery; Michel Ephritikhine;
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Service de Chimie Moleculaire, DSM, DRECAM, CNRS URA 331, CEA Saclay, 91191 Gif- sur-Yvette, France;

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正文语种 eng
中图分类化学;
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Unprecedented reduction of the uranyl ion [UO_2]~(2+) into a polyoxo uranium(Ⅳ) cluster: Synthesis and crystal structure of the first f-element oxide with a M_6(μ_3-O)_8 core

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