A Ru(terpy)(phen)-incorporating ring and its light-induced geometrical changes

Sylvestre Bonnet; Jean-Paul Collin; Jean-Pierre Sauvage

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A Ru(terpy)(phen)-incorporating ring and its light-induced geometrical changes

机译：含Ru（terpy）（phen）的环及其光诱导的几何变化

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摘要

A Ru(terpy)(phen) motif has been inscribed in a 39-membered ring by functionalizing the ligands and subsequently performing a cyclization reaction on the complex; by visible light irradiation, a dramatic geometrical changeover of the cyclic complex takes place which can be reversed thermally.

机译：通过对配体进行官能化，然后对复合物进行环化反应，将Ru（terpy）（phen）基序题为39元环。通过可见光照射，发生了环状配合物的剧烈几何变化，该变化可以热逆转。

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来源
《Chemical Communications》 |2005年第25期|p.3195-3197|共3页
作者
Sylvestre Bonnet; Jean-Paul Collin; Jean-Pierre Sauvage;
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作者单位

Laboratoire de Chimie Organo-Minerale, UMR 7513 du CNRS, Inslitut Le Bel. Universite Louis Pasteur, 4 rue Blaise Pascal, 67000 Strasbourg Cedex, France;

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正文语种 eng
中图分类化学;
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1. Construction of Interlocking and Threaded Rings Using Two Different Transition Metals as Templating and Connecting Centers: Catenanes and Rotaxanes Incorporating Ru(terpy)_2-Units in Their Framework [J] . Diego J. Cardenas, Pablo Gavina, Jean-Pierre Sauvage Journal of the American Chemical Society . 1997,第11期

机译：使用两种不同的过渡金属作为模板和连接中心构造互锁环和螺纹环：链烷和轮烷在其框架中结合Ru（terpy）_2-单元
2. Ruthenium-Decorated Lipid Vesicles: Light-Induced Release of [Ru(terpy)(bpy)(OH_2)]~(2+) and Thermal Back Coordination [J] . Sylvestre Bonnet, Bart Limburg, Johannes D. Meeldijk, Journal of the American Chemical Society . 2011,第2期

机译：钌修饰脂质囊泡：[Ru（terpy）（bpy）（OH_2）]〜（2+）的光诱导释放和热背配位
3. Synthesis and Photochemistry of a Two-Position Ru(terpy)(phen)(L)~(2+) Scorpionate Complex [J] . Sylvestre Bonnet, Jean-Paul Collin, Jean-Pierre Sauvage Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2006,第10期

机译：二元Ru（terpy）（phen）（L）〜（2+）蝎形配合物的合成与光化学
4. X-Ray Excited Optical Luminescence from Ru(bipy)_3~(2+) and Ru(phen)_3~(2+) in the Energy and Time Domains [C] . Simone Lam, Franziskus Heigl, P.-S. Grace Kim, International Conference on X-ray Absorption Fine Structure . 2007

机译：来自ru（bipy）_3〜（2+）和ru（phen）_3〜（2+）的X射线激发光学发光在能量和时间域中
5. Thermodynamic Studies of the Binding of RPC2, ([Ru(Ph2phen)3]2+), to Purified Tubulin and Microtubules [D] . West, Savannah J. 2019

机译：RPC2的结合的热力学研究，（[Ru（pH2phen）3] 2+），纯化管蛋白和微管
6. Successive light-induced two electron transfers in a Ru–Fe supramolecular assembly: from Ru–Fe(ii)–OH2 to Ru–Fe(iv)–oxo [O] . Christian Herrero, Annamaria Quaranta, Marie Sircoglou, 2015

机译：Ru-Fe超分子组装中的连续光诱导的两个电子转移：从Ru-Fe（ii）-OH2到Ru-Fe（iv）-氧代
7. A new luminescent Ru(terpy) complex incorporating a 1,2,4-triazole based σ-donor ligand [O] . Duati, Marco, Fanni, Stefano, Vos, Johannes G. 2000

机译：一种新的发光Ru（terpy）配合物，结合了1,2,4-三唑基σ-供体配体
8. Picosecond infrared study of intramolecular energy transfer in ((phen)(CO)(sub 3)Re(sup I)(NC)Ru(sup II)(CN)(bpy)(sub 2))(sup +). [R] . R. B. Dyer K. A. Peterson K. C. Gordon W. H. Woodruff J. R. Schoonover 1992

机译：在（（phen）（CO）（sub 3）Re（sup I）（NC）Ru（sup II）（CN）（bpy）（sub 2））（sup +）中的分子内能量转移的皮秒红外研究。

A Ru(terpy)(phen)-incorporating ring and its light-induced geometrical changes

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