Photoinduced DNA end capping via N~3-methyl-5-cyanovinyl-2′-deoxyuridine

Kenzo Fujimoto; Yoshinaga Yoshimura; Tadayoshi Ikemoto; Akio Nakazawa; Masayuki Hayashi; Isao Saito

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Photoinduced DNA end capping via N~3-methyl-5-cyanovinyl-2′-deoxyuridine

机译：N〜3-甲基-5-氰基ovylyl-2'-脱氧尿苷对DNA的光诱导封端

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摘要

A modified oligodeoxynucleotide (ODN) containing N~3-methyl-5-cyanovinyl-2′-deoxyundine reacts by photoirradiation at 366 nm with an adenine residue of a complementary template ODN to yield an end-capped ODN in 87% yield.

机译：含有N〜3-甲基-5-氰基ovyl-2'-脱氧金刚烷的修饰寡聚脱氧核苷酸（ODN）通过在366 nm处进行光辐照与互补模板ODN的腺嘌呤残基反应，以87％的产率产生封端的ODN。

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来源
《Chemical Communications》 |2005年第25期|p.3177-3179|共3页
作者
Kenzo Fujimoto; Yoshinaga Yoshimura; Tadayoshi Ikemoto; Akio Nakazawa; Masayuki Hayashi; Isao Saito;
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The School of Materials Science, Japan Advanced Institute of Science and Technology, Ishikawa, 923-1292, Japan;

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正文语种 eng
中图分类化学;
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2. DHPLC and MS studies of a photoinduced intrastrand cross-link in DNA labeled with 5-bromo-2'-deoxyuridine [J] . Justyna Wiczk, Justyna Miloch, Janusz Rak Journal of Photochemistry and Photobiology, B. Biology: Official Journal of the European Society for Photobiology . 2014,第Null期

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3. Synthesis of DNA oligonucleotides containing 5-(mercaptomethyl)-2'-deoxyuridine moieties. [J] . Bornemann B, Marx A Bioorganic and Medicinal Chemistry . 2006,第18期

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4. Enzymatic Synthesis of 5-Hydroxy-2′-deoxyuridine Oligomers toward DNA-templated Metal Assembly [C] . Tong Xing, Wenxuan Zhang, Takahiro Nakama 日本化学会春季年会講演予稿集 . 2018

机译：酶合成5-羟基-2'-脱氧尿苷的低聚物朝向DNA模板金属组件
5. Synthesis of several redox-active 2'-deoxyuridine nucleoside conjugates and spectroscopic studies of photoinduced electron transfer in pyrenyl-substituted uridine and several DNA hairpins. [D] . Gaballah, Samir Tawfik. 2003

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机译：人红细胞中包封的5-氟-2'-脱氧尿苷5'-单磷酸酯转化为抗肿瘤药5-氟-2'-脱氧尿苷。

Photoinduced DNA end capping via N~3-methyl-5-cyanovinyl-2′-deoxyuridine

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