Mechanistic studies of an unusual epoxide-forming elimination of a beta-hydroxyalkyl rhodium porphyrin

Han YZ; Sanford MS; England MD; Groves JT

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Mechanistic studies of an unusual epoxide-forming elimination of a beta-hydroxyalkyl rhodium porphyrin

机译：β-羟烷基铑卟啉异常环氧化物消除的机理研究

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摘要

A new and remarkably facile sp(3)-C-O bond forming reaction of beta-hydroxyalkyl Rh porphyrins to form epoxides has been discovered and its mechanism investigated.

机译：β-羟烷基Rh卟啉形成环氧化物的新的且非常容易的sp（3）-C-O键形成反应已被发现并对其机理进行了研究。

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来源
《Chemical Communications》 |2006年第5期|p. 549-551|共3页
作者
Han YZ; Sanford MS; England MD; Groves JT;
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作者单位

Princeton Univ, Dept Chem, Princeton, NJ 08544 USA;

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原文格式 PDF
正文语种 eng
中图分类化学;
关键词
O REDUCTIVE ELIMINATION; C-H BONDS; ARYL HALIDES; COMPLEXES; PALLADIUM; OXIDATION; ETHERS; ACTIVATION; MACROCYCLE; (ER)(2);

机译：O消除消除;C-H键;卤化芳烃;络合物;钯;氧化;醚;活化;大环;（ER）（2）;

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1. Reactivity and kinetic-mechanistic studies of regioselective reactions of rhodium porphyrins with unactivated olefins in water that form beta-hydroxyalkyl complexes and conversion to ketones and epoxides [J] . Zhang JD, Wayland BB, Yun L, Dalton transactions: An international journal of inorganic chemistry . 2010,第2期

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2. Mechanistic comparison of β-H elimination, β-OH elimination, and nucleophilic displacement reactions of β-hydroxy alkyl rhodium porphyrin complexes [J] . Wu B., Zhang J., Yun L., Dalton transactions: An international journal of inorganic chemistry . 2011,第10期

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Mechanistic studies of an unusual epoxide-forming elimination of a beta-hydroxyalkyl rhodium porphyrin

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