Removal of nickel(II) ions from aqueous solutions using the natural clinoptilolite and preparation of nano-NiO on the exhausted clinoptilolite

摘要

The natural zeolite tuff (clinoptilolite) from a Serbian deposit has been studied as adsorbent for Ni(II) ions from aqueous solutions. Its sorption capacity at 298K varies from 1.9mg Nig~(-1) (for the initial solution concentration of 100 mg Ni dm~(-3)) to 3.8 mg Ni g~(-1) (for C_0 = 600 mg Ni dm~(-3)) and it increases 3 times at 338 K. The sorption is best described by the Sips isotherm model. The sorption kinetics follows the pseudo-second-order model, the activation energies being 7.44,5.86,6.62 and 6.63 kj mol~(-1) for C_0 = 100,200,300 and 400 mg Ni dm~(-3), respectively. The sorption involves a film diffusion, an intra-particle diffusion, and a chemical cation-exchange between the Na~+ ions of clinoptilolite and the Ni~(2+) ions. The sorption is endothermic (ΔH° being 37.9, 33.4, 30.0, 27.7 and 24.3 kj mol~(-1) for C_0 = 100, 200, 300,400 and 600 mg Ni dm~(-3), respectively) and spontaneous in the 298-338 K temperature range. Thermal treatment of the Ni(II)-loaded clinoptilolite results in the formation of spherical nano-NiO particles of approx. 5nm in diameter which are randomly dispersed in the clinoptilolite lattice.