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Removal of conventional and novel taste and odour compounds from drinking water using UV photolysis and UV/hydrogen peroxide advanced oxidation.

机译:使用紫外线光解和紫外线/过氧化氢高级氧化去除饮用水中的传统和新颖的味觉和气味化合物。

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摘要

Taste and odour (T&O) has always been of concern in the drinking water industry because consumers that perceive T&O may not drink the water for aesthetic reasons or they may associate the T&O with the water not being safe to consume. The two terpenoids, geosmin and 2-methylisoborneol (MIB), are the most common compounds linked to odour outbreaks of the earthy, musty, and moldy category, while 2-isopropyl-3-methoxypyrazine (IPMP) and 2-isobutyl-3-methoxypyrazine (IBMP) are identified less often. As a result, the majority of research using UV photolysis and the advanced oxidation process (AOP) of UV in combination with hydrogen peroxide (UV/H2O 2) have been conducted on the conventional T&O compounds geosmin and MIB. All these compounds can be detected by humans at exceptionally low concentrations (i.e. low parts-per-trillion) and have been frequently reported during the late summer/early fall in several potable waters including the Great Lakes.; Some more novel T&O compounds include unsaturated aldehydes such as E2-heptenal, E2,E4-nonadienal, E2,E4-decadienal, and E2,E4-heptadienal (i.e. aldehydic compounds). These compounds have been measured in various source waters and identified as odourous compounds in the fruity, fishy, and swampy categories They have odour threshold concentrations (OTCs) that range from the parts-per-trillion to parts-per-billion range. Todate, there has been limited research conducted on the ability for UV and UV/H2O 2 to destroy aldehydic compounds. Furthermore, conventional treatment processes have difficulty removing these traditional and novel T&O compounds to below their respective OTCs.; The focus of this research was to explore the potential for UV and UV/H 2O2 to remove conventional and novel T&O compounds from potable waters. The bench-scale experiments demonstrated significant removal of all the compounds of interest even when implementing a hydrogen peroxide dose as low as 1.5 mg/L and an UV fluence greater than 500 mJ/cm2 for a given water quality. Furthermore, UV/H2O2 was shown to have the ability to remove geosmin, MIB, IPMP, and IBMP up to 2 times greater than with only direct UV photolysis. Moderate removal with direct UV photolysis was achieved for the aldehydic compounds. Conventional treatment prior to UV or UV/H2O2 did not change the water quality enough to effect T&O removal in this investigation (i.e. raw versus treated water results were similar), but this would be expected to be source-specific. Geosmin, MIB, and the pyrazines were most resistant to treatment in the bench-scale studies, regardless of whether or not hydrogen peroxide was present.; It was identified that UV photolysis may be capable of mitigating the aldehydic compounds thereby eliminating the need for a hydroxyl-radical driven process and, thus, the need to add and then quench hydrogen peroxide before secondary disinfection at a WTP. Residual hydrogen peroxide from the UV/H 2O2 AOP would exert a chlorine demand for secondary disinfection. Therefore, implementing only UV photolysis for the control of odourous aldehydes would provide an economic benefit to a WTP because chemical costs would be minimized as opposed to using the AOP of UV/H2O2. In agreement with previous experiments, it was demonstrated that in order to efficiently mitigate geosmin, MIB, and the pyrazines an AOP would likely be needed.; Experimental results from varying the hydrogen peroxide dose while implementing UV fluences that are typically used for disinfection of micro-organisms (40 to 200 mJ/cm2), demonstrated that high concentrations of hydrogen peroxide would be required to mitigate the conventional and novel T&O compounds. A log reduction close to or exceeding 1 was achieved for only the aldehydic compounds E2,E4-nonadienal, E2,E4-heptadienal, and E2,E4-decadienal at the highest hydrogen peroxide dose of 26 mg/L. The hydrogen peroxide experiments verified that the hydroxyl radical-driven reactions contribute only partially to the reduction
机译:味道和气味(T&O)在饮用水行业中一直备受关注,因为认为T&O的消费者出于审美原因可能不喝水,或者他们可能将T&O与不安全饮用的水联系起来。两种萜类化合物土臭素和2-甲基异冰片醇(MIB)是最常见的化合物,与土类,霉菌和发霉类的气味爆发有关,而2-异丙基-3-甲氧基吡嗪(IPMP)和2-异丁基-3-甲氧基吡嗪(IBMP)的识别频率较低。结果,大多数使用UV光解和UV与过氧化氢(UV / H2O 2)结合使用UV的高级氧化过程(AOP)的研究都针对常规的T&O化合物geosmin和MIB。所有这些化合物都可以被人类以极低的浓度(即,低至万亿分之一)检测到,并已在夏末/初秋期间在包括五大湖在内的若干饮用水中被频繁报道。一些更新颖的T&O化合物包括不饱和醛,例如E2-庚烯醛,E2,E4-壬二烯醛,E2,E4-癸二烯醛和E2,E4-庚二烯醛(即醛类化合物)。这些化合物已在各种水源中进行了测量,并被确定为果味,鱼腥和沼泽类中的异味化合物。它们的气味阈值浓度(OTC)范围从万亿分之几到十亿分之几。迄今为止,关于UV和UV / H 2 O 2破坏醛类化合物的能力的研究有限。此外,常规的处理方法难以将这些传统的和新颖的T&O化合物去除到其各自的OTC以下。这项研究的重点是探索UV和UV / H 2O2去除饮用水中常规和新型T&O化合物的潜力。实验室规模的实验表明,即使在给定的水质下,过氧化氢的剂量低至1.5 mg / L且UV通量大于500 mJ / cm2时,也能显着去除所有目标化合物。此外,显示出UV / H2O2具有比仅直接UV光解作用高出2倍的去除土臭素,MIB,IPMP和IBMP的能力。醛类化合物可通过直接UV光解进行中度去除。在此研究中,使用UV或UV / H2O2之前的常规处理不会改变水质,不足以影响T&O的去除(即,原水与处理后的水的结果相似),但是这将取决于来源。无论在实验室中是否存在过氧化氢,Geosmin,MIB和吡嗪对治疗的耐受性最高。可以确定的是,紫外线光解可以减轻醛类化合物的含量,从而消除了对羟基自由基驱动工艺的需要,从而消除了在WTP进行二次消毒之前先添加然后淬灭过氧化氢的需要。 UV / H 2O2 AOP中残留的过氧化氢会产生二次消毒所需的氯。因此,仅实施UV光解以控制臭味醛将为WTP提供经济利益,因为与使用UV / H2O2的AOP相比,化学成本将降至最低。与先前的实验一致,证明了为了有效减轻土臭素,MIB和吡嗪的作用,可能需要AOP。通过改变过氧化氢的剂量,同时实现通常用于微生物消毒的紫外线通量(40至200 mJ / cm2)的实验结果表明,需要高浓度的过氧化氢来减轻传统和新型的T&O化合物。在最高26 mg / L的过氧化氢剂量下,仅醛类化合物E2,E4-壬二烯醛,E2,E4-庚二烯醛和E2,E4-癸二烯醛的对数减少量接近或超过1。过氧化氢实验证明,羟基自由基驱动的反应仅部分有助于还原

著录项

  • 作者

    Gray, Scott Lindsay.;

  • 作者单位

    University of Waterloo (Canada).;

  • 授予单位 University of Waterloo (Canada).;
  • 学科 Engineering Civil.; Engineering Sanitary and Municipal.; Engineering Environmental.
  • 学位 M.A.Sc.
  • 年度 2006
  • 页码 156 p.
  • 总页数 156
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 建筑科学;建筑科学;环境污染及其防治;
  • 关键词

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