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The Vertical Migration Model and Recent Advances in Geochemical Exploration

机译:地球化学勘探的垂直迁移模型与最近进展

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Petroleum geochemical exploration is the science of using geochemical measurements to assess information about petroleum reservoirs before drilling. Vertical migration is the foundation of all geochemical exploration methods. Vertical migration provides the geochemical communication link between subsurface reservoirs and the surface. Vertical migration is the foundation of petroleum geochemical exploration. Geochemical exploration techniques began about 85 years ago in Russia and about 10 years later in the USA. Horvitz (1939) described the measurement of petroleum gases in shallow soil samples in Harris, Brazoria, and Galveston counties, Texas. Since that time, geochemical exploration methods have proven successful both onshore and offshore in the Gulf Coast area. Brooks et aL (1986) reported that they achieved the most success for sampling liquid hydrocarbons offshore, including the Gulf of Mexico, over the surface expressions of seismically determined faults. The faults were thought to provide conduits for petroleum to travel from reservoir depths to ocean-bottom sediments. Although surface expressions of vertical migration were known and documented throughout the last 75 years, the mechanisms by which hydrocarbons could move from reservoirs to the surface were not known (Horvitz, 1978). Diffusion and other vertical migration models could not explain the surface hydrocarbon expressions nor could they explain why migration was primarily vertical. About 20 years ago the industry developed a buoyancy mechanism (Fig. 1) modeled by Klusman and Saeed (1996). Below the water table, gases migrate vertically as a gas phase with buoyancy providing a mechanism for predominately vertical migration. The buoyancy model explains the gradients and data contrasts observed in many surface geochemical features. Arp (1992) quantified the buoyancy-driven migration mechanism in a form that calculated vertical migration rates. Vertical migration rates predicted by the model were verified by field measurements. The buoyancy model therefore explained most of the observations from vertical migration data. When the vertical migration model was extended to petroleum liquids, we found that liquid hydrocarbons could migrate similarly to gases, but slower and through larger fractures and faults. Each phase (gas or liquid) provides information about reservoir composition. Different surface expressions of these two migrating phases form the basis of modern geochemical exploration. An added benefit from liquid hydrocarbon geochemical exploration data is reservoir petroleum fluid characterization from exploration measurements prior to drilling. A seismic/geochemical integration project reported by Belt and Rice (1996) in the Main Pass area, shallow offshore Louisiana, was instrumental in understanding the liquid hydrocarbon migration mechanism. A cross section of the Main Pass data in Figure 2 shows gas concentration data in green represented by ethane C_2) concentration. Liquid hydrocarbon concentrations, measured by a fluorescence technique (3-ring C_(14) to about C_(18)) are in magenta. While petroleum liquids appeared to migrate up faults, gases migrated up visible faults and also between faults. Most of this gas migration would have been through fractures too small to be visible on the seismic section. As predicted by the vertical migration model, gas migration is possible about everywhere over a petroleum reservoir.
机译:石油地球化学勘探是使用地球化学测量来评估钻井前的石油储层信息的科学。垂直迁移是所有地球化学勘探方法的基础。垂直迁移提供了地下储存器和表面之间的地球化学通信联系。垂直迁移是石油地球化学勘探的基础。地球化学勘探技术在大约85年前在俄罗斯和大约10年后在美国。 Horvitz(1939)描述了德克萨斯州哈里斯,崎岖和加尔维斯顿县的浅层土样品中的石油气体测量。从那时起,地球化学勘探方法已经成功地成功地在海湾海岸地区的陆上和海上。 Brooks等人(1986)据报道,他们在地震所确定的故障的表面表达上实现了对紫外线的液体碳氢化合物的紫外线取样最多成功。认为缺陷是为石油提供从水库深度到海底沉积物的管道。尽管在过去75年中,垂直迁移的表面表达是已知并记录的,但是碳氢化合物可以从储存器到表面移动的机制(Horvitz,1978)。扩散和其他垂直迁移模型无法解释表面碳氢化合物表达,也不能解释为什么迁移主要是垂直的。大约20年前,该行业发展了由Klusman和Saeed(1996)建模的浮力机制(图1)。水表下方,气体垂直迁移,作为气相,浮力为主要垂直迁移提供机制。浮力模型解释了许多表面地球化学特征中观察到的梯度和数据对比。 ARP(1992)以计算垂直迁移率的形式量化了浮力驱动的迁移机制。通过现场测量验证了模型预测的垂直迁移率。因此,浮力模型从垂直迁移数据中解释了大多数观察。当垂直迁移模型扩展到石油液体时,我们发现液体烃可以类似地迁移到气体中,但较慢,越来越大的骨折和故障。每个阶段(气体或液体)提供有关储层组合物的信息。这两种迁移阶段的不同表面表达构成了现代地球化学勘探的基础。液态烃地球化学勘探数据的增加的益处是钻井前勘探测量的储层石油流体表征。皮带和大米(1996)报道的地震/地球化学集成项目在主通道区域,浅海上路易斯安那州,在理解液态碳氢化合物迁移机制方面是有乐器。图2中主通过数据的横截面显示了由乙烷C_2)浓度表示的绿色的气体浓度数据。通过荧光技术(3环C_(14)至约C_(18))测量的液态烃浓度在洋红色中。虽然石油液体似乎迁移了故障,但气体迁移了可见的断层,也涉及故障。大多数这种气体迁移将通过骨折太小而无法在地震部分可见。如垂直迁移模型所预测的那样,在石油储存器上有可能对气体迁移。

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