Theoretical study of Co-C bond dissociation reactions by B12-TiO2

机译：B12-TiO2 CO-C键离解反应的理论研究

获取原文

页面导航

摘要
著录项
相似文献
相关主题

摘要

A CoI complex of the cobalamin derivatives (B12) has a high reactivity to organic halides with supernucleophilicity. Recently a new catalytic system of B12 immobilized on the surface of TiO2 was reported. The new B12-TiO2 hybrid catalyst undergoes the dechlorination of chlorinated organic compounds because of a strong CoI nucleophile.

机译：钴胺蛋白衍生物（B12）的COI复合物对具有上核的有机卤化物具有高反应性。最近，报道了一种新的B12催化系统，其固定在TiO 2表面上。新的B12-TiO2杂交催化剂由于强COI亲核试剂，经历氯化有机化合物的脱氯。

著录项

来源
《日本化学会春季年会講演予稿集》|2018年|1 CD-ROM|共1页
会议地点
作者
Kenji Imamura; Yoshihi to Shiota; Kazunari Yoshizawa;
展开▼
作者单位

展开▼
会议组织
原文格式 PDF
正文语种
中图分类石油化学工业;
关键词
B12-TiO2 hybrid catalyst; Dechlorination; SN2 reactions; Transition State; DFT calculation;

机译：B12-TiO2杂交催化剂;脱氯;SN2反应;过渡状态;DFT计算;

相似文献

外文文献
中文文献
专利

1. Co-C bond dissociation energy and reaction volume change of 2 ',5 '-dideoxyadenosylcobalamin studied by laser-induced time-resolved photoacoustic calorimetry [J] . Chen H., Li G., Zhang FF., Spectrochimica acta, Part A. Molecular and biomolecular spectroscopy . 2003,第12期

机译：激光诱导时间分辨光声量热法研究2'，5'-二脱氧腺苷钴胺素的Co-C键解离能和反应体积变化
2. Theoretical Study of Two Possible Side Reactions for Reductive Functionalization of 3d Metal-Methyl Complexes by Hydroxide Ion: Deprotonation and Metal-Methyl Bond Dissociation [J] . Fallah Hengameh, Horng Floyd, Cundari Thomas R. Organometallics . 2016,第7期

机译：氢氧根离子对3d金属-甲基配合物进行还原功能化的两种可能的副反应的理论研究：去质子化和金属-甲基键解离
3. Computational study on the difference between the Co-C bond dissociation energy in methylcobalamin and adenosylcobalamin [J] . Dolker N, Morreale A, Maseras F Journal of biological inorganic chemistry: JBIC: a publication of the Society of Biological Inorganic Chemistry . 2005,第5期

机译：甲基钴胺素和腺苷钴胺素中Co-C键解离能差异的计算研究
4. Theoretical study of Co-C bond dissociation reactions by B12-TiO2 [C] . Kenji Imamura, Yoshihi to Shiota, Kazunari Yoshizawa 日本化学会春季年会講演予稿集 . 2018

机译：B12-TiO2 CO-C键离解反应的理论研究
5. Experimental and theoretical studies of binding interactions in divalent transition metal cation-N-donor ligand complexes: Structures, sequential bond dissociation energies, mechanisms and energetics of collision-induced dissociation. [D] . Nose, Holliness. 2014

机译：二价过渡金属阳离子-N-供体配体配合物中结合相互作用的实验和理论研究：结构，顺序键解离能，碰撞诱导解离的机理和能量。
6. Theoretical Bond Dissociation Energies of Halo-Heterocycles: Trends and Relationships to Regioselectivity in Palladium-Catalyzed Cross-Coupling Reactions [O] . Yeimy Garcia, Franziska Schoenebeck, Claude Y. Legault, -1

机译：晕杂环的理论键离解能：趋势和关系到区域选择性钯催化交叉偶联反应
7. How the Co-C Bond Is Cleaved in Coenzyme B12 Enzymes: A Theoretical Study [O] . -1

机译：CO-C键如何以辅酶B12酶裂解：理论研究
8. Theoretical study of the C-H bond dissociation energy of acetylene [R] . Taylor, Peter R., Bauschlicher, Charles W., Jr., Langhoff, Stephen R. 1990

机译：乙炔C-H键解离能的理论研究

Theoretical study of Co-C bond dissociation reactions by B12-TiO2

摘要

著录项

相似文献

相关主题

期刊订阅