Synthesis of platinum(IV)porphyrin diselenocyanate and its selenocyanation reactivity on arenes

摘要

Metallo-porphyrins (MPor) play important roles in the current research of chemistry, because of their versatile functions such as electron transfer, energy transfer, magnetism, and so on. These properties are controlled by the central metal, peripheral substituents, and the axially coordinated ligands. In this study, we focused on ligation reactions on Pt(IV) porphyrins because this metal tends to form stable bond with ligands.