Synthesis and crystal structure of dinuclear based coordination polymer derived from N-6-(4-pyridylmethylamino)carbonyl-2-pyridinecarboxylic acid methyl ester

摘要

This study describes the facile synthesis and crystal structure of one dimensional coordination polymer which has been successfully obtained from reaction between semi rigid monoamide ligand namely N-6-[(4-pyridylmethylamino)carbonyl]-2-pyridinecarboxylic acid methyl ester (L2) with copper perchlorate. The synthesized coordination polymer, with formula given by elemental analysis and X-ray crystallography as {[Cu3(L2-CH3)3(L2)2(H2O)2(CH3OH)](C1O4)3}_n was crystallized in monoclinic crystal system and space group C2/c. The asymmetric unit of this complex consists of three copper atoms, three anionic carboxylate forms of ligand L2, two neutral forms of ligand L2 and four partially-occupied non-coordinated perchlorate anions. This asymmetric unit acts as the repeating fragment to form one-dimensional networks which was stabilized by intramolecular hydrogen bonds.