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Utilization of Duck Eggshell and Chicken Eggshell as Catalyst for Biodiesel Synthesis from Waste Cooking Oil

机译:利用鸭蛋壳和鸡蛋壳作为废物烹饪油生物柴油合成催化剂

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Nowadays, the increasing need for energy fuels threatens up to the extinction of fossil fuels and increases pollution. Therefore, it is necessary to develop alternative energy that is environmentally friendly and easily produced such as biodiesel. Biodiesel can be produced from substances that contain fatty acids through transesterification reaction with alcohol and base catalysts. In this study, used waste cooking oil is used as a source of fatty acids and CaO catalysts synthesized from duck eggshells and chicken eggshells. The result shows that the transesterification reaction worked optimally with 5 % weight of catalyst, 600 W of microwave energy, 40 seconds of reaction time and methanol to oil molar ratio of 1:15. The biodiesel products obtained were characterized by gas chromatography-mass spectrometry (GC-MS) and were a methyl ester compound such as methyl palmitate, methyl stearate, methyl 9-octadecenoate, methyl 2-hydroxy hexanoate and hydroxypropyl methyl oleic.
机译:如今,越来越需要能量燃料的需求威胁到化石燃料的灭绝并增加污染。 因此,有必要开发替代能源,这些能量是环保且易于生产的诸如生物柴油。 生物柴油可以由含有醇化反应与醇和基催化剂的含脂肪酸的物质制成。 在这项研究中,使用的废物烹饪油用作由鸭蛋壳和鸡蛋壳合成的脂肪酸和CaO催化剂来源。 结果表明,酯交换反应最佳地用5%重量的催化剂,600W微波能量,40秒的反应时间和甲醇与油摩尔比为1:15。 得到的生物柴油产品的表征是通过气相色谱 - 质谱(GC-MS)的特征,并是甲酯化合物,如甲基棕榈酸酯,硬脂酸甲酯,9-十八烷酸甲酯,甲基2-羟基己酸酯和羟丙基甲基油。

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