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Synergistic Flame Retardant Effect of Fumed Silica and Zinc Borate with Magnesium Hydroxide in ABS Based Flame Retardant Composites

机译:吸气二氧化硅和氢氧化镁基氢氧化镁在肥大阻燃复合材料中的协同阻燃效应

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摘要

For achieving sufficient flame retardancy, high magnesim hydroxide (MH) content is needed in MH flame retardant Acrylonitrile-butadiene-styrene copolymer (ABS) composite (ABS/MH), which will cause difficulty in processing and poor mechanical property. We prepared modified flame retardant MH, fumed silica (SiO_2) and zinc borate (ZB) via TX-10 phosphate/polyacrylate latex as well as MH flame retardant ABS with the modified flame retardant of 60.0wt% and studied the synergistic flame retardant effect of SiO_2 and ZB with MH in ABS/MH. The incorporation of ZB, SiO_2 or SiO_2/ZB could prolong the time to ignition, reduce the average and peak heat release rate of ABS/MH in cone calorimeter test.
机译:为了实现足够的阻燃性,在MH阻燃丙烯腈 - 丁二烯 - 苯乙烯 - 苯乙烯共聚物(ABS)复合(ABS / MH)中需要高镁氢氧化物(MH)含量,这将导致加工和机械性能差。通过TX-10磷酸盐/聚丙烯酸酯胶乳以及MH的阻燃剂的改性阻燃剂的60.0wt%,制备改性阻燃MH,气相二氧化硅(SiO_2)和锌硼酸锌(Zb),并研究了协同阻燃效果sio_2和zb在abs / mh中mh。 Zb,SiO_2或SiO_2 / ZB的掺入可以延长点火时间,降低锥形量热仪测试中ABS / MH的平均和峰值热释放速率。

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