Crystallitic structure and thermodynamics of magnesium-based hydrogen storage materials from reactive milling under hydrogen atmosphere

摘要

Magnesium-based hydrogen storage materials were prepared by reactive milling of magnesium under hydrogen atmosphere with crystallitic carbon, prepared from anthracite coal, as milling aid. The XRD analysis shows that in the presence of 30 wt.% of crystallitic carbon, the Mg easily hydrided into β-MgH_2 of crystal grain size 29.7 nm and a small amount of γ-MgH_2 after 3 h of milling under 1 MPa H_2. The enthalpy and entropy changes of the hydrogen desorption reaction are 42.7 kJ/mol and 80.7 J/mol K, respectively, calculated by the van't Hoff equation from the p-C-T data in 300-380°C.