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Tungsten Carbides as Alternative Electrocatalysts: From Surface Science Studies to Fuel Cell Evaluation

机译:碳化钨作为替代电催化剂:从表面科学研究到燃料电池评估

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The use of fuel cells for energy applications has seen many advances over the past few decades However, technical hurdles remain for the large scale commercialization of the fuel cell technology. For example, for direct methanol fuel cells (DMFC) the main challenges associated with the anode electrocatalysts are (1) the high cost of Pt and Ru, which are the leading DMFC electrocatalysts, and (2) the strong binding of CO molecules on the Pt and Ru surfaces, which block active sites necessary for the electro-oxidation of CH3OH. Therefore, the commercialization of DMFC depends upon the development of new catalytic materials that should be more cost effective and show lower binding energy for adsorbed CO.
机译:然而,使用燃料电池的能源应用已经看到过去几十年的进步,然而,技术障碍仍然是燃料电池技术的大规模商业化。例如,对于直接甲醇燃料电池(DMFC)与阳极电催化剂相关的主要挑战是(1)Pt和Ru的高成本,即前导DMFC电催化剂,(2)CO分子对CO分子的强粘合Pt和Ru表面,阻止了CH 3 OH的电氧化所需的活性位点。因此,DMFC的商业化取决于新型催化材料的开发,该催化材料应更具成本效益,并显示吸附CO的较低的结合能量。

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