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Biomass-Derived Porous Nitrogen-ContainingCarbonaceous Materials

机译:生物质衍生的多孔氮碳碳酸盐材料

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Recently, the production of porous carbon materials by using low cost precursor as well as sustainable approach is one of the most appealing topics in materials science. Several groups have paid their attention to the use of biomass-derived carbohydrates or even raw biomass to synthesis carbonaceous structures.1,2,3 Nevertheless, for some applications, surface functionalization/bulk dopant is required. Doping of the carbon material structure with heteroatoms (e.g. N, S, B, etc.) is a popular route to tune both the structural and physicochemical properties. Among these, nitrogen-doped porous carbons exhibited remarkable performance in some applications, such as gas sorption, purification, catalysts and in electrochemistry (e.g. as supercapacitors, fuel cells and batteries).4,5Herein, our recent research regarding facile approaches for the production of nitrogen-rich porous carbons will be presented. A series of nitrogen-doped carbon materials were obtained by using biomass (e.g. human hair, shrimp shells, or chinese tofu, etc.) as precursors via simple procedures, such as hydrothermal carbonization, dehydration, activation. In this extend abstract, we will focus on the discussion of the human hair-derived nitrogen and sulfur co-doped porous carbon materials. Herein, the human hair-derived materials were synthesized via a degradation and carbonization/activation process.The as-prepared porous materials possess very high specific surface areavalues and exhibit superior performance in gas sorption.
机译:最近,通过使用低成本前体以及可持续方法的多孔碳材料的生产是材料科学中最吸引人的主题之一。几个群体对使用生物质衍生的碳水化合物或甚至原料生物质来合成碳质结构的使用,因此对于一些应用,需要表面官能化/散装掺杂剂。用杂原子(例如,N,S,B等)的掺杂碳材料结构是曲线的途径,以调节结构和物理化学性质。其中,氮气掺杂的多孔碳碳在一些应用中表现出显着的性能,例如气体吸附,纯化,催化剂和电化学(例如作为超级电容器,燃料电池和电池).4,5氏,我们最近关于生产的易于生产方法的研究将呈现富含氮的多孔碳。通过使用生物量(例如人头,虾壳或中国豆腐等)作为前体获得一系列氮掺杂的碳材料,例如水热碳化,脱水,活化。在这种延伸摘要中,我们将专注于对人头源氮和硫共掺杂多孔碳材料的讨论。在此,通过降解和碳化/活化过程合成人头源性材料。制备的多孔材料具有非常高的比表面积,并且在气体吸附中表现出优异的性能。

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