Chemical Compositions of Manganese Nodules - In Situ Microenergy Dispersive X-Ray Fluorescence (mu-EDXRF) and Bulk Data

摘要

Ferromanganese nodules form a specific category of widespread marine mineral deposits. The tremendous increase in metal prices during the last decade raised new economic interest in their exploration. The German Federal Institute for Geosciences and Natural Resources (BGR), which had been engaged in nodule research in the 1970s and 1980s, renewed its activities on this subject based on an exploration contract with the International Seabed Authority, signed in 2006. BGR's licence area -comprising 75 000 km~2 - is located between the Clarion and the Clipperton Fracture Zones. In this so-called nodule belt north of the equator the sea floor reaches water depths of >4000 m. About 900 million tonnes of manganese nodules are expected there. In this study the fine-scale distribution of important elements in manganese nodules and crusts from a variety of locations was investigated. Besides 11 samples from the RV SONNE cruise SO-25, numerous samples from additional locations were included in this study for comparison. In general, the sample suite includes two genetic types of precipitates, manganese nodules and Co-rich crusts.