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STUDY ON THE STRUCTURE AND ACTIVITY OF DISPERSED NI CATALYST FOR SLURRY BED HYDROCRACKING OF RESIDUE

机译:浆料床加氢裂化分散Ni催化剂的结构与活性研究

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In the technique of slurry bed hydrocracking for heavy oil, catalysts are highly dispersed in the feedstock oil and suspend in the reactor. In this technique, catalyst is playing an important role in two ways: preventing residue from coke formation by releasing activated hydrogen; on the other hand, catalysts granules could be used as carriers, and unloaded out of the reactors with coke together. Coke sedimenting on the surface of the catalyst could cover the reactive center, and reduce coke-restraining ability of the catalyst. Therefore, examination about deactivation condition of water-soluble catalyst in slurry bed hydrocracking helps us know about activity changes of catalyst during the reaction and choose a proper reaction space velocity. What’s more , study on catalyst activities at different reaction time makes it sense to determine reaction condition of slurry bed hydrocracking technology.
机译:在浆料床加氢裂化的技术中,催化剂在原料油中高度分散并悬浮在反应器中。在该技术中,催化剂以两种方式发挥重要作用:通过释放活化的氢气防止残余物。另一方面,催化剂颗粒可以用作载体,并用焦炭卸下反应器。在催化剂表面上的焦炭沉淀可以覆盖反应性中心,并降低催化剂的焦炭限制能力。因此,关于浆料床加氢裂化中的水溶性催化剂的去激活条件的检查有助于我们知道反应期间催化剂的活性变化,并选择适当的反应空间速度。更重要的是,对不同反应时间的催化剂活性的研究使得测定浆料床加氢裂化技术的反应条件是有意义的。

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