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Synthesis and magnetic properties of rare-earth free MnBi alloy: A high-energy hard magnetic material

机译:稀土自由锰合金的合成和磁性:高能硬磁材料

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MnBi is a rare-earth free high-energy magnetic material useful for the permanent magnet based devices. In a simple method, a MnBi alloy was prepared by arc melting method using Mn and Bi metals in 60:40 atomic ratio. In terms of the X-ray diffraction, a crystalline MnBi phase is formed with Bi as impurity phase of the as-prepared alloy. FESEM image of chemically etched sample shows small grains throughout the alloy. SEAD pattern and lattice image were studied to understand the internal microstructure of the alloy. The thermomagnetic curves measured in ZFC-FC cycles over 5-380 K temperatures at 500 Oe field, shows the induced magnetization of 5-25 % in the sample. The coercivity values, 7.455 kOe (13.07 emu/g magnetization) at 380 K, and 5.185k Oe (14.75 emu/g magnetization) at 300 K, are observed in the M-H hysteresis loops. A decreased value 0.181kOe (18.05 emu/g magnetization) appears at 100 K due to the change in the magnetocrystalline anisotropy. The results are useful to fabricate small MnBi magnets for different permanent magnets based devices.
机译:MNBI是一种可用于永磁磁铁的装置的稀土式高能磁性材料。在一种简单的方法中,通过在60:40原子比中使用Mn和Bi金属的电弧熔化方法制备MnBi合金。就X射线衍射而言,用BIA作为制备合金的杂质相形成结晶MnBi相。化学蚀刻样品的FeSEM图像显示了整个合金的小颗粒。研究了SEAD图案和晶格图像以了解合金的内部微观结构。在500 OE场的ZFC-FC循环中测量的热磁曲线在500 OE场的温度下,显示出样品中的诱导磁化为5-25%。在M-H滞后环中观察到矫顽力值,7.455koe(13.07 emu / g磁化)在380k和5.185k Oe(14.75 ee / gmem / g磁化)中观察到。由于磁镀各向异性的变化,减少0.181koe(18.05 emu / g磁化)出现在100 k处。结果对于制造基于不同的永磁体的小型MnBi磁体是有用的。

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