Corrosivity and Corrosion Inhibiting Characteristics of Sulfonate-functionalized Triethylammonium and Pyridinium-type Brønsted Acidic Ionic Liquids

摘要

The corrosion bebavior of mild steel in two Brønsted acidic ionic liquids (BAILs) with different cationic centers, triethylammonium and pyridinium-type, was electrochemically investigated in nonaqueous and aqueous conditions at 25°C. A relatively wide passivation region (0-2.1 V) was clearly observed for mild steel, along with a lower corrosion rate, for both BAILs at 25°C. The Bronsted acidity of these BAILs is not proportional to the corrosion rate of the tested mild steel specimens. In addition, the different adsorption centers on each BAIL molecule, namely their sulfonate group along with either a quaternary ammonium or pyridinium structural motif, means they can possess different inhibiting characteristics as well as modes of adsorption at metal surfaces. Based on these electrochemical results, the inhibition ability of both BAILs in 0.5 M HCI solution against acid corrosion of mild steel was investigated, at various concentrations at 25°C, using gravimetric measurements. The pyridinium-type sulfonate-functionalized IL did not contribute to corrosion protection of the steel surface, while the triethylammonium-type sulfonate-functionalized IL had an inhibition efficiency of ca. 40%.