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Brønsted acidic room temperature ionic liquids each having a N-protonated lactam cation and method for preparing the same

机译:均具有 N 质子化内酰胺阳离子的布朗斯台德酸性室温离子液体及其制备方法

摘要

The invention relates to a class of novel Brønsted acidic ionic liquids each having a lactam cation, and to a method for preparing the same through simple neutralization reaction of a lactam, which is available in large scale from industry, with a Brønsted inorganic or organic acid under room temperature. The properties of the lactam Brønsted acidic ionic liquids are as follows: they are water- and moisture-stable; they are more environmentally benign and lower cost than that of dialkylimidazolium salts; they have stronger Brønsted acidity and can be used as acidic catalysts and media instead of inorganic corrosive acids, such as concentrated sulfuric acid and hydrofluoric acid, in many acid-catalyzed reactions; and they can also be used as green media for extraction and separation.
机译:本发明涉及各自具有内酰胺阳离子的一类新颖的布朗斯台德酸性离子液体,以及通过内酰胺的简单中和反应制备其的方法,所述内酰胺与布朗斯台德的无机或有机酸可从工业上大规模地获得。在室温下。内酰胺布朗斯台德酸性离子液体的特性如下:它们对水和湿气稳定;与二烷基咪唑鎓盐相比,它们在环境方面更有利,成本更低。它们具有更强的布朗斯台德酸度,可在许多酸催化反应中用作酸性催化剂和介质,代替浓硫酸和氢氟酸等无机腐蚀性酸。它们还可用作提取和分离的绿色介质。

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