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Growth Kinetics of CdSe Nanoparticles in Lauric Acid

机译:月桂酸中CdSe纳米粒子的生长动力学

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摘要

A safe, common, and low-cost method was proven to be effective for the synthesis of high quality CdSe nanocrystals. Cd(Ac)_2 and Lauric acid were found to be the excellent cadmium precursor and solvent/ligand, respectively. The size and shape of CdSe nanocrystals synthesized by this route can be varied in a controllable manner in a broad size range, from about 2.0 nm to 4 nm. The growth kinetics of CdSe nanocrystals nucleated from TOPSe and cadmium acetate was also investigated in Laurie Acid. The rate constant for steady-state CdSe growth was found to be 4.15×10~(-8)m s~(-1) at 260℃.
机译:事实证明,一种安全,通用且低成本的方法对于合成高质量的CdSe纳米晶体是有效的。发现Cd(Ac)_2和月桂酸分别是优良的镉前体和溶剂/配体。通过这种途径合成的CdSe纳米晶体的尺寸和形状可以在约2.0nm至4nm的宽尺寸范围内以可控制的方式变化。还从Laurie Acid中研究了由TOPSe和乙酸镉成核的CdSe纳米晶体的生长动力学。在260℃下,CdSe稳态生长的速率常数为4.15×10〜(-8)m s〜(-1)。

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