combustion

摘要： The accelerated depletion of oil reserves and the often exorbitant cost of fossil fuels contribute to the development of fuels from renewable sources. The objective of this work is to analyze the influence of the properties of renewable fuels on their evaporation in natural convection, their combustion and their use in internal combustion engines. A summary of the various numerical and experimental works from the literature has been presented in this work. This work focuses on the numerical modelling of the natural convection evaporation of an isolated drop of a liquid fuel in natural convection. The transfers in the liquid and vapour phases are described by the conservation equations of mass and species, momentum and energy. The main feature of this work is the consideration of advection, azimuthal angle and thickness of the vapour phase of the drop during evaporation of the drop.

摘要： The main source of energy for most African families remains firewood. The exploitation of this resource is the main cause of accelerated environmental degradation with its consequences which are climate change and soil impoverishment. However, agricultural residues are often available and even abandoned in fields after harvest. In this regard, we have characterized three biomass with no economic value in order to use them for the production of biochar to improve soil quality while providing the energy necessary for household cooking. Our research was based on the following biomasses: cotton stalks, maize rachis and rice husks. The study made it possible to characterize the biomasses which could be used for combustion and/or pyrolysis. From the results obtained, we could observe a high ash content in the rice husk (24.21%) against 2.41% for cotton stalks and 2.00% for maize rachis. These results influence the calorific value of the rice husk, thus allowing it to be used matter in pyrolysis and not in combustion. In addition, cotton stalks and corn rachis can be used both as fuel and as biomass to be pyrolyzed.

摘要： Recycle of plastic waste is an indisputable means to alleviate both environment and energy crisis.In this work,effects of heating condition on polyethylene behaviors in nitrogen and air were studied.It was observed that polyethylene behavior was a single step in nitrogen,while the multiple steps occurred in air.According to the weight loss and heat flow curves,polyethylene behaviors in air were divided into three regions:low-temperature( 380 °C) regions.Kinetic analysis revealed that the partial oxidization took the dominance in the low-temperature region,which seldom formed CO and CO_(2);the combustion took the dominance in the middle-temperature region,which was positive to the formation of CO and CO_(2);the pyrolysis was initiated and enhanced in the high-temperature region,which inhibited the formation of CO and CO;.According to the kinetic simulation,a synergistic effect between the pyrolysis and combustion was proposed to account for the acceleration of polyethylene conversion.This work may provide useful information about polyethylene behaviors under heating condition,and help to design and optimize plastic waste incineration process.

摘要： In this study,a one-dimensional simulation was performed to evaluate the performance of in-cylinder combustion to control NO_(x) emissions on a four-stroke,six-cylinder marine medium-speed diesel engine.Reducing the combustion temperature is an important in-cylinder measure to decrease NO_(x) emissions of marine diesel engines.The Miller cycle is an effective method used to reduce the maximum combustion temperature in a cylinder and accordingly decrease NO_(x) emissions.Therefore,the authors of this study designed seven different early intake valve closing(EIVC)Miller cycles for the original engine,and analyzed the cycle effects on combustions and emissions in high-load conditions.The results indicate that the temperature in the cylinder was significantly reduced,whereas fuel consumption was almost unchanged.When the IVC was properly advanced,the ignition delay period increased and the premixed combustion accelerated,but the in-cylinder average pressure,temperature and NO_(x) emissions in the cylinder were lower than the original engine.However,closing the intake valve too early led to high fuel consumption.In addition,the NO_(x) emissions,in-cylinder temperature,and heat release rate remarkably increased.Therefore,the optimal timing of the EIVC varied with different loads.The higher the load was,the earlier the best advance angle appeared.Therefore,the Miller cycle is an effective method for in-engine NO_(x) purification and does not entail significant cost.

摘要： One option to fight global warming is to convert our use of fossil energy into renewables such as biomass energy.However,the forest preservation and the quality of the ambient air are also two major issues.Therefore,the use of biomass waste without any supplementary emissions could represent a part of the solution.In this study,two fuels were considered for a 200 kW moving grate boiler.A multicyclone and a bag filter were fitted on the boiler.The first fuel consisted of classical wood chips whereas the second was a mixture of wood chips with sewage sludge.This second fuel presented a high ashes mass ratio compared to wood chips.The aim was to verify the possibility to burn this kind of fuel without any modification of the installation.The first relevant result is that the conventional pollutants,i.e.,CO and NOx,remained under the emissions limits even with the sewage sludge combustion.The Total Suspended Particles emissions at the exhaust were always under 5.4 mg·Nm-3 dry based corrected at 6%of O_(2),which is low with respect to the standard limitation.The majority of the ashes remained on the combustion room.However,with both fuels,about 5%of ashes mass remained in the heat exchanger.Nevertheless,the heat exchanger was more clogged with the second fuel,which produced five time more ashes.This may lead to a yield loss.Thus,sewage sludge can be used in a wood boiler without any issue if an automatic exchanger sweep is fitted on the installation.

摘要： Diesel engine alternative fuels, such as methanol and biodiesel, are beneficial to reduce diesel engine emission. In order to study the influence of methanol and biodiesel on the performance, economy and emission of small agricultural diesel engine, the physical-chemical properties(cetane number, lower heat value(LHV), viscosity, etc.) of methanol and biodiesel were analyzed. The methanol and biodiesel showed good complementary property to some extent. When a large proportion of methanol was added into biodiesel, the cetane number of the methanol/biodiesel blend will be greatly reduced. Since the cetane number of the blend fuel has great influence on the combustion process of diesel engine, after testing for blending ratio of methanol/biodiesel, the blend was prepared with 5%(BM5), 10%(BM10) and 15%(BM15) methanol, respectively. Di-Tert-Butyl Peroxide(DTBP) was chosen as a cetane number improver to be added into methanol/biodiesel blend. 0.25%, 0.50% and 0.75% of DTBP was added into BM15. The bench test was carried out on a 186 FA diesel engine to study the effect of methanol and DTBP on the engine performance and emissions. The results show that, at rated condition, compared with biodiesel, the NO;concentration of BM5, BM10 and BM15 is reduced by 5.02%, 33.85% and 21.24%, and smoke is reduced by 5.56%, 22.22% and 55.56%. However, the engine power is also reduced by 5.77%, 14.23% and 25.41%, and the brake specific energy consumption is increased by 3.31%, 7.78% and 6.37%. The addition of DTBP in methanol/biodiesel could recover the engine power to the level of diesel. DTBP shows good effect on the reduction of the brake specific energy consumption and NO_(x), CO, HC concentration, but a little increase of exhaust smoke.

摘要： Progress in the rocket industry is only possible on the basis of new, higher performance and more environmentally friendly materials compared to up-to-date propellant ingredients for liquid, solid, gelled and hybrid propellant systems. In this work, synthetic methods have been developed for the preparation of new energetic azofurazans bearing nitroxymethyl or azidomethyl groups. All prepared compounds were fully characterized by multinuclear NMR and IR spectroscopies, as well as elemental analyses. An analysis of the structural features based on the X-ray single-crystal diffraction made it possible to discuss their influence on the densities of the azofurazans of this study. Thermal decomposition and combustion of nitroxymethyl and azidomethyl azofurazans were studied using a number of complementary experimental techniques, namely thermogravimetry, differential scanning calorimetry, manometry, microthermocouple measurements in the combustion wave. The structural and physical characteristics of these new energetic analogues illustrate the extent to which the nature of the explosophoric groups can be used to tune the performace of the azofurazan framework. These azofurazans possess positive calculated enthalpy of formation and are promising candidates for new environmentally friendly energetic materials.

摘要： The effective recycling of waste printed circuit boards(WPCBs)can conserve resources and reduce environmental pollution.This study explores the pyrolysis and combustion characteristics of WPCBs in various atmospheres through thermogravimetric and Gaussian fitting analyses.Furthermore,this study analyses the pyrolysis products and combustion processes of WPCBs through thermogravimetric and Fourier transform infrared analyses(TG-FTIR)and thermogravimetry-mass spectrometry(TG-MS).Results show that the pyrolysis and combustion processes of WPCBs do not constitute a single reaction,but rather an overlap of multiple reactions.The pyrolysis and combustion process of WPCBs is divided into multiple reactions by Gaussian peak fitting.The kinetic parameters of each reaction are obtained by the Coats-Redfern method.In an argon atmosphere,pyrolysis consists of the overlap of the preliminary pyrolysis of epoxy resin,pyrolysis of small organic molecules,and pyrolysis of brominated flame retardants.The thermal decomposition process in the O_(2) atmosphere is mainly divided into two reactions:brominated flame retardant combustion and epoxy combustion.This study provided the theoretical basis for pollution control,process optimization,and reactor design of WPCBs pyrolysis.

摘要： The effect of swirl number(Sn)on the flow behavior and combustion characteristics of a lean premixed propane FlameФ=0.5 in a swirl burner configuration was numerically verified in this study.Two-dimensional numerical simulations were performed using ANSYS-Fluent software.For turbulence closure,a standard K-εturbulence model was applied.The turbulence-chemistry interaction scheme was modeled using the Finite Rate-Eddy Dissipation hybrid model(FR/EDM)with a reduced three-step reaction mechanism.The P1 radiation model was used for the flame radiation inside the combustion chamber.Four different swirl numbers were selected(0,0.72,1.05,and 1.4)corresponding to different angles(0°,39°,50°,and 57.8°).The results show that the predicted model agrees very well with the experimental data,especially with respect to the axial and radial velocity and temperature profiles.An outer recirculation zone(ORZ)is present in the combustor corner at Sn=0 and an inner recirculation zone(IRZ)appears at the combustor centerline inlet at a critical Sn=0.72.When the Sn reaches an excessive value,the IRZ moves toward the premixing tube,leading to a flame flashback.The flame structure and its length are strongly affected by changes in the Sn as well as the formation of NOx and CO at the combustor exit.

摘要： 城市固体废物(Municipal Solid Wastes,MSW)综合管理的主要方法为物资回收、能量回收、经生物转化为燃料和肥料以及残渣的填埋。本文对经预处理的MSW中可燃成分的能量回收进行了研究,并在适当设计的燃烧反应装置及热电联供的热电厂以它们作为燃料进行了探讨。尽管MSW中物质多种多样,但其平均碳氢化合物的结构可以近似用有机化合物C6H/4表示。推出的公式可以预测作为水分及玻璃/金属含量函数的MSW的热值,并堪比实验值。美国一座性能领先的废物-能源(Wastes-to-Energy)电厂MSW的年处理量约为90万吨,每吨MSW的净发电量为620kWh.此项研究的结果表明,从MSW中回收能量可以大大减少每年用于填埋的土地量,还可减少对化石燃料的依赖程度。