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Ring-opening polymerization process for cyclo-lactone compound and metal-porphyrin catalyst for ring-opening polymerization

机译:环形内酯化合物的开环聚合方法和开环聚合的金属卟啉催化剂

摘要

The ring-opening polymerization method of a lactone-based compound according to the present invention is a ring-opening polymerization method in which polymerization proceeds by ring-opening of a lactone compound as a monomer, and under a benzyl alcohol initiator and an amine compound reaction system, metal-porphyrin as a catalyst To provide a ring-opening polymerization method of a lactone-based compound, characterized in that the polymerization. The ring-opening polymerization method according to the present invention has an advantage in that the synthesis reaction is improved through the metal porphyrin catalyst, and a polylactone aliphatic alkyl ester having an excellent yield (% conversion) and a high molecular weight can be prepared.
机译:根据本发明的内酯基化合物的开环聚合方法是开环聚合方法,其中通过作为单体的内酯化合物的开环进行聚合,并且在苄醇引发剂和胺化合物下进行 反应系统,金属卟啉作为催化剂,以提供内酯基化合物的开环聚合方法,其特征在于聚合。 根据本发明的开环聚合方法的优点在于,通过金属卟啉催化剂改善合成反应,可以制备具有优异产率(百分比转化)和高分子量的聚丙酮脂族烷基酯。

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