首页> 外国专利> BIODEGRADABLE POLYURETHANE FOAM, BIODEGRADABLE POLYURETHANE FOAM-BASED MATERIAL FOR SACCHARIDE-CLEAVING ENZYME PRODUCTION, METHOD OF SYNTHESIS AND USE THEREOF

BIODEGRADABLE POLYURETHANE FOAM, BIODEGRADABLE POLYURETHANE FOAM-BASED MATERIAL FOR SACCHARIDE-CLEAVING ENZYME PRODUCTION, METHOD OF SYNTHESIS AND USE THEREOF

机译:可生物降解的聚氨酯泡沫,可生物降解的聚氨酯泡沫基用于糖切割酶生产,合成方法及其用途

摘要

The present invention relates to a method of synthesis of a biodegradable polyurethane foam, comprising the following steps: i) mixing of at least one aliphatic isocyanate bearing at least two isocyanate groups with at least one saccharide in weight ratio of from 1:1 to 30:1 to form a saccharide-isocyanate precursor; ii) homogenization of the saccharide-isocyanate precursor from step i) with 20 to 70 % (w/w) of at least one biodegradable aliphatic polyester-ether polyol having molecular mass in the range of from 0 to 10 000 g/mol and hydroxyl number from 10 to 100 mgKOH/g, 1 to 5 % (w/w) of water, and 1 to 10 % (w/w) of at least one blowing agent other than water, related to the total weight of the resulting mixture; iii) foaming of the homogenized mixture from step ii) at the temperature of from 20 to 100 °C, resulting in the biodegradable polyurethane foam comprising incorporated saccharide. The invention further relates to a biodegradable polyurethane foam obtainable by this method, to a biodegradable polyurethane foam-based material for saccharide-cleaving enzyme production and to the use thereof.
机译:本发明涉及一种合成可生物降解的聚氨酯泡沫的方法,包括以下步骤:i)至少一种含有至少两个异氰酸酯基团的脂族异氰酸酯的混合,其中至少一种具有至少一种重量比为1:1至30的糖类:1形成糖 - 异氰酸酯前体; ii)来自步骤i)的糖类 - 异氰酸酯前体的均质化,20至70%(w / w)的至少一种可生物降解的脂族聚酯 - 醚多元醇的分子量为0-1000g / mol和羟基从10至100mgKOH / g,1至5%(w / w)的水,1至10%(w / w)除水以外的至少一种发泡剂,与所得混合物的总重量有关; III)从步骤II)在20至100℃的温度下从步骤II的均化混合物发泡,导致可生物降解的聚氨酯泡沫包含掺入糖类。本发明还涉及可通过该方法获得的可生物降解的聚氨酯泡沫,其可用于可生物降解的聚氨酯泡沫基材料,用于糖类裂解酶产生和用途。

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