BIOACTIVE PEPTIDE BRUSH POLYMERS VIA PHOTOINDUCED REVERSIBLE-DEACTIVATION RADICAL POLYMERIZATION
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机译:通过光态可逆停用自由基聚合的生物活性肽刷子聚合物
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摘要
Aspects of the invention include a method for synthesizing a peptide brush polymer, the method comprising: exposing a mixture comprising peptide-containing monomers, one or more photoinitiators, and one or more chain transfer agents to a light sufficient to induce photopolymerization, and photopolymerizing the peptide-containing monomers in the mixture; wherein: the resulting peptide brush polymer comprises at least one peptide-containing polymer block; the at least one peptide-containing polymer block is characterized by a degree of polymerization of at least 10 and a peptide graft density of 50% to 100%; and at least one peptide moiety of the at least one peptide-containing polymer block has 5 or more amino acid groups.
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