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Method for setting polymerization conditions, method for manufacturing optical materials

机译:设定聚合条件的方法,制造光学材料的方法

摘要

In the method for setting polymerization conditions of the present invention, a polymerization-reactive compound containing an episulfide compound and a composition containing a polymerization catalyst are heated, and the functional group before heating of the polymerization-reactive compound is heated at a predetermined temperature. The physical property acquisition step (S10) of acquiring the derived physical property value a and the property value b derived from the residual functional group after keeping the temperature for a predetermined period of time (S10), the residual functional group rate calculation step (S20) of calculating the residual functional group rate from the property value a and the property value b, and , From the residual functional group rate, a reaction rate coefficient calculation step (S30) of calculating a reaction rate coefficient based on a reaction rate equation, and polymerization based on a reaction rate equation using the reaction rate coefficient so as to satisfy the following conditions. A polymerization condition setting method comprising a polymerization temperature calculation step (S40) of inverting each polymerization temperature at predetermined time intervals within time. (Condition) In the range of polymerization rate of 0% or more and 20% or less, the polymerization rate exceeds 0%/hr and is 3.0%/hr or less, and the standard deviation is 0.8%/hr or less.
机译:在本发明的聚合条件的方法中,加热含有外观化合物和含有聚合催化剂的组合物的聚合反应性化合物,并在加热聚合反应性化合物之前加热官能团在预定温度下加热。在将温度保持一段预定时间段(S10)之后,获取从残留官能组的派生物理性质值A和来自残留功能组的属性值B的物理性质获取步骤(S10)(S20从属性值A和属性值B计算残留官能团速率,并且从残留官能团速率,基于反应速率方程计算反应速率系数的反应速率系数计算步骤(S30),基于使用反应速率系数的反应速率方程的聚合,以满足以下条件。一种聚合条件设定方法,包括在时间内以预定的时间间隔反转每个聚合温度的聚合温度计算步骤(S40)。 (条件)在聚合速率范围为0%以上且20%以下,聚合速率超过0%/ hr,3.0%/ hr或更小,标准偏差为0.8%/ hr或更低。

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