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PROCESS FOR THE PRODUCTION OF alpha-SUBSTITUTED BENZOINS AND BENZOIN ETHERS
PROCESS FOR THE PRODUCTION OF alpha-SUBSTITUTED BENZOINS AND BENZOIN ETHERS
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机译:生产α-取代的苯甲醚和苯甲醚的过程
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摘要
Procedure for obtaining the benzoin derivatives of formula I: **(See formula)** where R1 is the same or different from R2 and R1 and R2 signify hydrogen, alkyl, alkoxy and/or halogen and R3 signifies alkyl, alkenyl, cycloalkyl, aryl or aralkyl, R4 signifies hydrogen, alkyl, alkenyl, cycloalkyl, aryl or aralkyl and X signifies oxygen or sulfur, characterized in that compounds of formula II; **(See formula)** they are reacted in the presence of bases, preferably aqueous bases, in dipolar aprotic solvents, preferably dialkyl sulfoxides, at temperatures between about 0 and 100 °, preferably around 30ºC, with electrophilic agents. (Machine-translation by Google Translate, not legally binding)
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机译:获得式I的安息香衍生物的步骤:**(参见式)**其中R1与R2相同或不同,R1和R2表示氢,烷基,烷氧基和/或卤素,R3表示烷基,烯基,环烷基, R 4表示芳基或芳烷基,R 4表示氢,烷基,烯基,环烷基,芳基或芳烷基,X表示氧或硫,其特征在于式II的化合物; **(参见公式)**,它们在碱(优选为水性碱)的存在下,在偶极非质子传递溶剂(优选为二烷基亚砜)中,在约0至100°C,优选在约30ºC的温度下与亲电子试剂反应。 (通过Google翻译进行机器翻译,没有法律约束力)
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