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PROCESS FOR RECOVERING MERCURY AND ACTIVATED CHARCOAL FROM ACTIVATED CHARCOAL/MERCURIC CHLORIDE-TYPE DEACTIVATED CATALYSTS

机译:从活性炭/氯化汞型失活催化剂中回收汞和活性炭的方法

摘要

The invention relates to a continuous process for recovering mercury chloride and acrylic support from commercial mercury / activated charcoal catalyst catalysts by auto-controlled burning of the activated catalyst in a gas stream containing 0 , 2 ... 5% vol oxygen at combustion temperatures of 420 ... 560 degrees C linear gas velocities of 0.1 ... 50 cm / s solid state residence times in the reactor of 0.1 ... 10 hours at normal pressure when mercuric chloride is recovered as metallic mercury with a yield of 97 ... 99% by weight and the active carbon support in a yield of 80 ... 90% by weight having optimal structure and texture properties for its reuse in the initial catalyst manufacture.
机译:本发明涉及一种连续方法,其通过在燃烧温度为0、2〜5%vol的氧气流中自控燃烧活性催化剂来从商业汞/活性炭催化剂催化剂中回收氯化汞和丙烯酸载体。当氯化汞以金属汞的形式回收时,在常压下420〜560℃线性气体速度为0.1 ... 50 cm / s,在反应器中固态停留时间为0.1 ... 10小时,回收率为97。 .. 99%的重量和80%至90%的产率的活性炭载体具有最佳的结构和织构特性,可在初始催化剂生产中重新使用。

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