首页> 外国专利> METHOD OF METALLIC IONES CU(II),PB(II),HG(II),CD(II),NI(II),ZN(II),SR(II),LA(III),UO2 2+, TH(IV) REMOVAL FROM AQUEOUS SOLUTIONS

METHOD OF METALLIC IONES CU(II),PB(II),HG(II),CD(II),NI(II),ZN(II),SR(II),LA(III),UO2 2+, TH(IV) REMOVAL FROM AQUEOUS SOLUTIONS

机译:金属离子的测定方法CU(II),PB(II),HG(II),CD(II),NI(II),ZN(II),SR(II),LA(III),UO2 2 +,TH( IV)从水溶液中去除

摘要

The method applies to the removal of metallic ions such as Cu(II), Pb(II), Hg(II), Cd(II), Ni(II), Zn(II), Sr(II), La(III), UO22+, Th(IV) from aqueous solutions with the subsequent regeneration of used tenside is that the tensides of type C-alkyl amide of ethylenediaminetetraacetic acid with alkyl C6 to C20 act on the aqueous solutions of metals so that a ratio of tenside and metal is 1:1 to 3 in the extent of pH 1 to 7, while a separable precipitate of the metal complex with tenside arises either directly, or the pH necessary for the creation of precipitate is achieved by adding mineral acids, such as sulphuric acid, nitric acid, hydrochloric acid (hydrogen chloride), and subsequently by adding the foresaid mineral acids in a concentration of 1 to 5 moles x dm-3 to the isolated precipitate of the complex. Metallic ion is isolated in the form of a soluble inorganic salt under simultaneous precipitation of the original tenside. By the method described, 80 to 99.9 mass % of metal is removed from the aqueous solutions, and by a subsequent regeneration of tenside, 90 to 99 mass % of the original tenside is possible to obtain for repetitive use.
机译:该方法适用于去除金属离子,例如Cu(II),Pb(II),Hg(II),Cd(II),Ni(II),Zn(II),Sr(II),La(III)水溶液中的,UO2 2+,Th(IV)以及随后再生用过的表面活性剂是乙二胺四乙酸的C-烷基酰胺型C6至C20烷基的表面活性剂作用于金属水溶液表面活性剂与金属的比例在pH 1至7的范围内为1:1至3,而金属表面活性剂与表面活性剂的可分离沉淀物直接产生,或通过添加无机酸获得产生沉淀物所需的pH值,例如作为硫酸,硝酸,盐酸(氯化氢),然后通过将浓度为1至5摩尔x dm -3的上述山药矿物酸加入到该配合物中分离出的沉淀物中。在同时沉淀原始表面活性剂的情况下,以可溶性无机盐的形式分离出金属离子。通过所述的方法,从水溶液中去除了80至99.9质量%的金属,并且通过表面活性剂的随后再生,可以获得原始表面活性剂的90至99质量%以重复使用。

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