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Liquid absorbing sour gases containing a tertiary alkanolamine component and a CO2 absorption activator and its application to the deacidification of gas containing CO2 and optionally other sour gases

机译:含有叔链烷醇胺组分和CO2吸收活化剂的吸收液体的酸性气体,及其在含CO2气体和其他酸性气体的脱酸中的应用

摘要

Liquid absorbing acidic gaseous compounds exhibiting an improved capacity for absorbing CO2, the said absorbing liquid containing one or more tertiary alkanolamines and a CO2 absorption activator. The activator consists of at least one amine compound corresponding to the formulae Y-(CnH2n)-NHR and R1-NH-(CnH2n)-OH, in which Y is a monovalent radical chosen from the group consisting of piperazyl, piperidyl, furyl, tetrahydrofuryl, thienyl, tetrahydrothienyl and -OR2 radicals, R is a radical R2 or a hydrogen atom, R1 denotes a C2-C6 monovalent hydrocarbon radical, R2 is a C1-C6, optionally hydroxylated, monovalent hydrocarbon radical and n is an integer ranging from 1 to 6. Application of the said absorbent liquid to the deacidification of gas containing CO2 and optionally of other acidic gaseous compounds, especially H2S and/or COS.
机译:吸收液体的酸性气体化合物表现出提高的吸收二氧化碳的能力,所述吸收液体包含一种或多种叔链烷醇胺和吸收二氧化碳的活化剂。活化剂由至少一种对应于式Y-(CnH2n)-NHR和R1-NH-(CnH2n)-OH的胺化合物组成,其中Y是选自哌嗪基,哌啶基,呋喃基的单价基团,四氢呋喃基,噻吩基,四氢噻吩基和-OR2基团,R是基团R2或氢原子,R1表示C2-C6一价烃基,R2是C1-C6,任选地被羟基化的一价烃基,n是一个整数参见图1至6。所述吸收剂液体用于脱除含有CO 2的气体以及任选地其他酸性气态化合物,特别是H 2 S和/或COS的酸化。

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