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Microbial collapsible thermoplastics moldings and its production manner

机译:微生物可塌缩热塑性塑料成型件及其生产方式

摘要

PURPOSE:To obtain a molded item of resin capable of breaking microorganism and also having excellent mechanical property and secondary workability by using aliphatic polyester resin as matrix resin and mixing and dispersing thermoplastic resin in said matrix at a predetermined ratio. CONSTITUTION:Aliphatic polyester resins are polycondensation product of polyhydric carboxylic acid and polyhydric alcohol, polycondensation product of hydroxy acid and ring-opening polymerization product of lactone, which are hydrolyzed by the action of lipase. Thermoplastic resins are those of olefin, styrene, vinyl, acryl, amide, etc. A mixture of 25-60wt.% of said aliphatic polyester and 75-40wt.% of thermoplastic resins is extruded under conditions satisfying the formulas I, II. Extrusion is difficult to perform where etaA500 and both the components are not sufficiently mixed where etaB/etaA=10 and molded items wherein polyester resin is used as matrix cannot be obtained where etaB/etaA1. Conditions which satisfy the formulas can be provided by suitably selecting molecular weights of resins used and components and compositions of aliphatic polyesters and thermoplastic resins.
机译:用途:通过使用脂族聚酯树脂作为基质树脂并将热塑性树脂以预定比例混合并分散在所述基质中,以获得能够破坏微生物并且还具有优异的机械性能和二次加工性的树脂模制品。组成:脂族聚酯树脂是多元羧酸和多元醇的缩聚产物,羟酸的缩聚产物和内酯的开环聚合产物,在脂肪酶的作用下被水解。热塑性树脂是烯烃,苯乙烯,乙烯基,丙烯酸,酰胺等的那些。在满足式I,II的条件下挤出25-60wt。%的所述脂族聚酯和75-40wt。%的热塑性树脂的混合物。在etaB / etaA <1的情况下,难以在ηA<500且两种成分不能充分混合的情况下进行挤出,而在etaB / etaA> = 10的情况下难以得到,而以聚酯树脂为基质的成型品难以获得。其满足式的条件可以通过适当地选择所使用的树脂和组分和脂族聚酯和热塑性树脂的组合物的分子量来提供。

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