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SORBENT BASED ON ZEOLITE, METHOD FOR ITS PREPARATION AND A DEVICE FOR WATER TREATMENT FOR RESIDENTIAL NEEDS

机译:基于沸石的吸附剂,其制备方法和用于居民生活用水的处理装置

摘要

The invention relates to using a sorbent on zeolite basemodified in a cation form with anion groups and/or complex-forminggroups applied which fills up equipment assembled on the inletside of the water supply mains and at the outlet to the hot waternetwork for residential needs. The sorbent is natural or syntheticzeolite mineral having suitable grain size distribution,containing sodium, ammonium or hydrogen cations OH-, HPO42-appliedanion complex-forming groups enabling the fixation of calcium, andmagnesium ion (ethylene-diamine-tetraacetic acid, oxalic acid,other organic acids or their salts). If removal of iron andmanganese ions is required from the water, iron oxide andmanganoxide compounds are applied on the zeolite sorbent. Thesorbent based on zeolite has very well developed surface. Itsmodification does not change its sorption, ion-exchange, catalyticand surface properties proper to the zeolite matrix and enablesthe desired reaction with other components and the environment Thepassing of water with hardness 5 HO (2 meq/l) through theequipment results in the occurance of ion-exchange reactionsreducing the calcium and magnesium ions content in it and tochanges of the hydrogen-carbonate ion concentration resulting inthe fixation of the calcium carbonate on the grains of the sorbentat the expense of crystallization in situ. In this way treated hotwater for residential needs is secured in the water supplynetwork.
机译:本发明涉及在阳离子改性的沸石基上使用吸附剂的阴离子基团和/或配合物形成基团的吸附剂的使用,该吸附剂填充了组装在供水主管入口侧和热水网络出口处的设备,以满足居民的需求。吸附剂是具有合适粒度分布的天然或合成沸石矿物,包含钠,铵或氢阳离子OH-,HPO42-形成丙二醛络合物的基团,能够固定钙和镁离子(乙二胺-四乙酸,草酸,其他有机酸或其盐)。如果需要从水中去除铁和锰离子,则将氧化铁和氧化锰化合物施加到沸石吸附剂上。基于沸石的吸附剂表面非常发达。它的改性不会改变其对沸石基体的吸附,离子交换,催化和表面性质,并且能够与其他组分和环境进行所需的反应。硬度为5 HO(2 meq / l)的水通过该设备会导致离子的产生交换反应减少了钙和镁离子的含量,并改变了碳酸氢根离子的浓度,从而导致碳酸钙固定在吸附剂的颗粒上,而以原位结晶为代价。通过这种方式,可以在供水网络中确保满足居民需求的经过处理的热水。

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